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The addition of initiator affects the crossover point of the storage modulus (solid line) and the loss modulus (dashed lined), which indicates curing. As initiator content increases, the reaction proceeds more quickly.

The approach is to use peroxides to modify the reaction kinetics in the production of polysiloxanes.  A radical initiator in the presence of a hydride-terminated polysiloxane will increase the rate of curing and reduce manufacturing costs.  At a minimum a formulation would contain a hydride-terminated polysiloxane, a platinum catalyst, and an initiator that generates radicals.  The content of…

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Livermore researchers have developed a method for implementing closed-loop control in extrusion printing processes by means of novel sensing, machine learning, and optimal control algorithms for the optimization of printing parameters and controllability. The system includes a suite of sensors, including cameras, voltage and current meters, scales, etc., that provide in-situ process monitoring…
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Machine Learning for Monitoring microfluidic microcapsules
LLNL researchers have developed a system that relies on machine learning to monitor microfluidic devices. The system includes (at least) a microfluidic device, sensor(s), and a local network computer. The system could also include a camera that takes real-time images of channel(s) within an operating microfluidic device. A subset of these images can be used to train/teach a machine learning…