Skip to main content
Image
LLNL researchers prepare an experiment in a spherical chamber at the High Explosives Applications Facility (HEAF)

LLNL has developed a method that adds a polyamine based crosslinker and an acid receptor, based on MgO nanoparticles into a polymer bonded PBX, where the polymer binder is a fluoropolymer containing vinylidene difluoride functionality.  Crosslinking kinetics can then be controlled by selecting an appropriate amine structure, pressing temperature and optionally the addition of a chemical…

Image
High Explosives Science, abstract smoke stock photo

LLNL researchers uses Additive Manufacturing (AM) to create reinforcing scaffolds that can be integrated with High Explosives (HE) or solid rocket fuel with minimal volume fraction. Its main benefit is to create stability in harsh field conditions.  Its secondary benefit is providing another method to finely tune blast performance or fuel burn. Creating complex shapes with structural…

Image
The addition of initiator affects the crossover point of the storage modulus (solid line) and the loss modulus (dashed lined), which indicates curing. As initiator content increases, the reaction proceeds more quickly.

The approach is to use peroxides to modify the reaction kinetics in the production of polysiloxanes.  A radical initiator in the presence of a hydride-terminated polysiloxane will increase the rate of curing and reduce manufacturing costs.  At a minimum a formulation would contain a hydride-terminated polysiloxane, a platinum catalyst, and an initiator that generates radicals. …