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Picture of SLA printed structures using 3D printable nitrile-containing photopolymer resins

LLNL’s invention is a photopolymerizable polymer resin that consists of one or more nitrile-functional based polymers. The resin is formulated for SLA based 3D printing allowing for the production of nitrile-containing polymer components that can then be thermally processed into a conductive, highly graphitic materials. The novelty of the invention lies in (1) the photo-curable nitrile-…

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Diffuse discharge circuit breaker with latching switch

A thyristor will stay conducting until the current through the device is zero (“current zero”) or perhaps slightly negative.  LLNL’s approach is to use the opticondistor (“OTV”) to force this current zero in order to force the device into an “off” state.  By combining a light-activated thyristor with an OTV, a noise-immune, high efficiency, high-power switching device can be constructed. The…

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A cross-sectional schematic of a diffused Ga2O3 photoconductive semiconductor switch (PCSS)

The researchers’ approach leverages the concept that dopants have high diffusivities in Ga2O3; the key lies in the selection of the appropriate dopant.  This LLNL invention describes two device types that employ this design:

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Examples of different UV exposure patterns printed from the same multi-material resin.  Darker yellow regions have higher UV exposure times leading to tougher regions.

LLNL researchers have developed an innovative and uniform single-pot polymer multi-material system, based on a combination of 3 different reactive chemistries.  By combining the three different constituent monomers, fine control of mechanical attributes, such as elastic modulus, can be achieved by adjusting the dosage of UV light throughout the additive manufacturing process.  This results in…

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Samples of optimized diamond switches

Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength. 

Characteristics of the LLNL-developed switch are as follows:

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Custom PCB design of a PCSS Laser Diode Driver

LLNL researchers have invented an ultrafast PCSS to drive a high-power laser diode with arbitrary pulse widths.  These devices operate by supplying a high voltage (>10 kV) to one side of the switch.  A short pulse of light illuminates the semiconductor, instantly turning it from highly resistive to highly conductive.

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A sample of micro-architectured graphene aerogel, made from one of the lightest materials on Earth, sits atop a flower.

To overcome challenges that existing techniques for creating 3DGs face, LLNL researchers have developed a method that uses a light-based 3D printing process to rapidly create 3DG lattices of essentially any desired structure with graphene strut microstructure having pore sizes on the order of 10 nm. This flexible technique enables printing 3D micro-architected graphene objects with complex,…

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twister oven component with reflective inner cylinder surface

U.S. Patent No. 11,555,965 describes LLNL’s invention of “Illumination Frustums” for photoconductive switches to capture and “frustrate” the light from leaving the frustum.  LLNL researcher’s latest novel invention, “Twister Oven”, achieves this by encouraging laser light absorption in a photo conductor material.  Light enters the oven twisting and reflecting, making near normal incident multi…

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A photoconductive switch made from a synthetic, chemical vapor deposition diamond under test

Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength.  The diamond material is chosen to be doped with substitutional nitrogen to act as a source of electrons.  The device architecture allows maximum light entering the aperture.  The top and bottom electrodes are made of ultra-wide bandgap (UWBG)…

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schematic of LLNL’s field emission photocathode device architecture with examples of tunable SiC surface micro- and nanostructures fabricated at LLNL

LLNL researchers faced this challenge by bridging the gap between VEDs and solid-state electronics (SSE).  Their approach was to create a hybrid vacuum microelectronic device (VMD) architecture that combines the properties of vacuum as the electronic medium and the compact form factor and manufacturing scalability of semiconductor microelectronic chips.

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Segments of transmission line lengths can be switched to open circuit (as shown) or shorted to the ground (not shown)

Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength.  The diamond material is specifically doped with substitutional nitrogen, which act as a source of electrons.  The device architecture allows maximum light entering the aperture.  The top and bottom electrodes are made of ultra wide band gap (UWBG)…

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Annular illumination on photo conductor by Conical Total Internal Reflection “CTIR” endcap

The approach is to use a custom-designed frustrum and attach it to the optical fiber that connects to the PCSS.  Light from the fiber enters the frustrum, spreads out, and enters the PCSS.  Any unabsorbed light re-enters the frustrum and, because of its geometry, reflects back into the PCSS itself with only a negligible fraction escaping from the fiber.  The shape of the novel frustrum is…

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multichannel_pyrometer

LLNL researchers have designed and tested performance characteristics for a multichannel pyrometer that works in the NIR from 1200 to 2000 nm. A single datapoint without averaging can be acquired in 14 microseconds (sampling rate of 70,000/s). In conjunction with a diamond anvil cell, the system still works down to about 830K.

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Nanoporus gold

By combining 3D printing and dealloying., researchers at LLNL have developed a method for fabricating metal foams with engineered hierarchical architectures consisting of pores at least 3 distinct length scales. LLNL’s method uses direct ink writing (DIW), a 3D printing technique for additive manufacturing to fabricate hierarchical nanoporous metal foams with deterministically controlled 3D…