LLNL researchers have developed a method to enhance the performance of polyelectrolyte membranes by using a humidity-controlled crosslinking process which can be applied to precisely adjust the water channels of the membrane.
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![Picture of SLA printed structures using 3D printable nitrile-containing photopolymer resins](/sites/default/files/styles/scale_exact_400x400_/public/2024-04/SLA%20printed%20structures%20using%203D%20printable%20nitrile-containing%20photopolymer%20resins.jpg?itok=cVxxoNNY)
LLNL’s invention is a photopolymerizable polymer resin that consists of one or more nitrile-functional based polymers. The resin is formulated for SLA based 3D printing allowing for the production of nitrile-containing polymer components that can then be thermally processed into a conductive, highly graphitic materials. The novelty of the invention lies in (1) the photo-curable nitrile-…
![Printed TPMS membrane structures using nanoporous photoresist](/sites/default/files/styles/scale_exact_400x400_/public/2023-12/Printed%20TPMS%20membrane%20structures.png?itok=siH1EwC9)
LLNL researchers have developed novel advanced manufactured biomimetic 3D-TPMS (triply periodic minimal surface) membrane architectures such as a 3D gyroid membrane. The membrane is printed using LLNL's nano-porous photoresist technology. LLNL’s 3D-TPMS membranes consist of two independent but interpenetrating macropore flow channel systems that are separated by a thin nano-porous wall. 3D-…
![Potential reactor configurations with printed TPMS scaffolds](/sites/default/files/styles/scale_exact_400x400_/public/2023-12/Reactor_Config_with_TPMS_scaffolds.png?itok=stDW7Z7n)
LLNL researchers have devised a set of design principles that facilitates the development of practical TPMS-based two fluid flow reactors.; included in the design are these new concepts:
![Filled (8,8) (left) and (15,15) (right) CNTs with [EMIM+][BF4- ] using SGTI with the proposed spliced soft-core potential (SSCP) approach](/sites/default/files/styles/scale_exact_400x400_/public/2023-10/Filled%20CNTs%20using%20SGTI.png?itok=Dy0ObN7i)
LLNL researchers have developed a novel simulation methodology using slow growth thermodynamic integration (SGTI) utilizing spliced soft-core interaction potential (SSCP). The approach to filling the molecular enclosures is a nonphysical one. Rather than filling the pores from the open ends this method creates steps in the algorithm that allow molecules to pass through the pore wall and…
![Livermore researchers support efforts to limit the need for rare-earth elements in U.S. clean-energy technologies.](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/Reducing%20Reliance%20on%20Critical%20Materials.png?itok=IuC6bH4r)
CMI—a DOE Energy Innovation Hub—is a public/private partnership led by the Ames Laboratory that brings together the best and brightest research minds from universities, national laboratories (including LLNL), and the private sector to find innovative technology solutions to make better use of materials critical to the success of clean energy technologies as well as develop resilient and secure…
![nanocomposite_aerogel.jpg nanocomposite_aerogel](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/nanocomposite_aerogel.jpg?itok=PuNPrvkg)
Livermore researchers have developed two novel TiCl4 based non-alkoxide sol-gel approaches for the synthesis of SiO2/TiO2 nanocomposite aerogels. Composite SiO2-TiO2 aerogels were obtained by epoxide-assisted gelation (EAG route) of TiCl4/DMF solution in the presence SiO2 aerogel particles. Additionally, the same TiCl4/DMF solution was employed to prepare SiO2@TiO2 aerogels by a facile one-…
![Nanoporus gold](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/nanoporus%20gold%20875x500.jpg?itok=A0gFmVPT)
By combining 3D printing and dealloying., researchers at LLNL have developed a method for fabricating metal foams with engineered hierarchical architectures consisting of pores at least 3 distinct length scales. LLNL’s method uses direct ink writing (DIW), a 3D printing technique for additive manufacturing to fabricate hierarchical nanoporous metal foams with deterministically controlled 3D…
![Batteryless Sensor](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/batteryless%20sensor.jpg?itok=OiEAlv22)
Chemical and biological sensors based on nanowire or nanotube technologies exhibit observable ultrasensitive detection limits due to their unusually large surface-to-volume architecture. This suggests that nanosensors can provide a distinct advantage over conventional designs. This advantage is further enhanced when the nanosensor can harvest its meager power requirements from the surrounding…
![energy_absorbing_material.jpg energy_absorbing_material](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/energy_absorbing_material.jpg?itok=UxNZ6nWH)
To overcome limitations with cellular silicone foams, LLNL innovators have developed a new 3D energy absorbing material with tailored/engineered bulk-scale properties. The energy absorbing material has 3D patterned architectures specially designed for specific energy absorbing properties. The combination of LLNL's capabilities in advanced modeling and simulation and the additive…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
Nanomaterials that are emerging out of cutting edge nanotechnology research are a key component for an energy revolution. Carbon-based nanomaterials are ushering in the "new carbon age" with carbon nanotubes, nanoporous carbons, and graphene nanosheets that will prove necessary to provide sustainable energy applications that lessen our dependence on fossil fuels.
Carbon aerogels (CAs)…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
LLNL has developed novel nanoporous carbon materials for the surface-stress-induced actuator technology. The morphology of these materials has been designed to combine high surface area and mechanical strength. The process allows for the fabrication of large monolithic pieces with low densities and high structural integrity. One actuation technology relies on electrochemically- induced changes…