Powder atomic layer deposition process is used to coat nanopowders of host materials (e.g. yttrium aluminum garnet) with optically active neodymium organometal precursor followed by O2/O3 RF plasma to convert to a single layer of Nd2O3. The process can be repeated to build arbitrarily thick layers with custom doping profiles and followed by post-…
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![Small-angle X-ray scattering (SAXS) data of crosslinked polyelectrolyte membrane films formed under different equilibrium humidity conditions](/sites/default/files/styles/scale_exact_400x400_/public/2024-04/SAXS%20data%20of%20crosslinked%20polyelectrolyte%20membrane%20films.png?itok=1bIMOhqO)
LLNL researchers have developed a method to enhance the performance of polyelectrolyte membranes by using a humidity-controlled crosslinking process which can be applied to precisely adjust the water channels of the membrane.
![Laser peening induces deep compressive stress, which significantly extends the service lifetime over any conventional treatment](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/laser%20peening%20inducing%20deep%20compressive%20stress.png?itok=oMzDBpkP)
This invention proposes using a pulse laser configured to generate laser pulses and a controller for controlling operation of the pulse laser. The controller is further configured to control the pulse laser to cause the pulse laser to generate at least one of the laser pulses with a spatiotemporally varying laser fluence over a duration of at least one of the laser pulses. The spatiotemporally…
![Adobe Stock image laser beam](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/stockimage_laserbeam.png?itok=U06HtIhR)
This invention proposes to engineer the current density along the length of a laser diode to overcome the penalty associated with non-uniformity resulting from asymmetry in the gain, photon or carrier density despite having uniform contact. Optimizing the current density profile enables diode lasers to operate with greater power conversion efficiency or operate with equivalent power conversion…
![Schematic showing mismatched coefficient of thermal expansion (CTE) coating](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/IL-13312_Schematic.png?itok=5MN8Mf-U)
This invention proposes to engineer the temperature dependence of the emission wavelength of LEDs and laser diodes. The approach is to use a strain-inducing coating to counteract the intrinsic temperature coefficient of the emission wavelength of the LED or laser diode device thereby rendering it athermal. This invention avoids additional complexity, size, weight and power dissipation of…
![Photoconductive Semiconductor Laser Diodes and LEDs](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/Photoconductive%20Semiconductor%20Laser%20Diodes%20and%20LEDs.png?itok=n50p3rOY)
This invention proposes a method to overcome the key limitation of electrically pumped lasers based on AlN, AlGaN, or AlInGaN, namely the lack of suitable shallow donor and acceptor dopants. As the band gap of these materials increases (and the emission wavelength decreases), both electrons and holes require greater thermal energies in order to ionize.
![Adobe Stock image laser beam](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/stockimage_laserbeam.png?itok=U06HtIhR)
Laser diode lensing effect can be substantially reduced by creating a pattern interface such that the substrate is only attached at the diode mesa. This is achieved by either creating a pattern solder joint and/or pattern substrate.
![Potential reactor configurations with printed TPMS scaffolds](/sites/default/files/styles/scale_exact_400x400_/public/2023-12/Reactor_Config_with_TPMS_scaffolds.png?itok=stDW7Z7n)
LLNL researchers have devised a set of design principles that facilitates the development of practical TPMS-based two fluid flow reactors.; included in the design are these new concepts:
![Filled (8,8) (left) and (15,15) (right) CNTs with [EMIM+][BF4- ] using SGTI with the proposed spliced soft-core potential (SSCP) approach](/sites/default/files/styles/scale_exact_400x400_/public/2023-10/Filled%20CNTs%20using%20SGTI.png?itok=Dy0ObN7i)
LLNL researchers have developed a novel simulation methodology using slow growth thermodynamic integration (SGTI) utilizing spliced soft-core interaction potential (SSCP). The approach to filling the molecular enclosures is a nonphysical one. Rather than filling the pores from the open ends this method creates steps in the algorithm that allow molecules to pass through the pore wall and…
![Livermore researchers support efforts to limit the need for rare-earth elements in U.S. clean-energy technologies.](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/Reducing%20Reliance%20on%20Critical%20Materials.png?itok=IuC6bH4r)
CMI—a DOE Energy Innovation Hub—is a public/private partnership led by the Ames Laboratory that brings together the best and brightest research minds from universities, national laboratories (including LLNL), and the private sector to find innovative technology solutions to make better use of materials critical to the success of clean energy technologies as well as develop resilient and secure…
![One embodiment of a solid-state lithium-air battery based on gyroid foams.](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/Li-Air%20Battery%20Gyroid%20Foam.jpg?itok=gPAwVj0O)
LLNL researchers have developed a new 3D printable lithium-air battery that uses a novel thin solid state ceramic electrolyte. LLNL’s invention overcomes the combined challenges of low power density and low cycle life in previously designed lithium-air batteries by using solid state electrolytes to achieve stability and multiscale structuring of the electrolyte to achieve low interfacial…
![creation of ultra-high energy density matter by an intense laser pulse](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/laser_update875.jpg?itok=793sEzmU)
![nanocomposite_aerogel.jpg nanocomposite_aerogel](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/nanocomposite_aerogel.jpg?itok=PuNPrvkg)
Livermore researchers have developed two novel TiCl4 based non-alkoxide sol-gel approaches for the synthesis of SiO2/TiO2 nanocomposite aerogels. Composite SiO2-TiO2 aerogels were obtained by epoxide-assisted gelation (EAG route) of TiCl4/DMF solution in the presence SiO2 aerogel particles. Additionally, the same TiCl4/DMF solution was employed to prepare SiO2@TiO2 aerogels by a facile one-…
![Nanoporus gold](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/nanoporus%20gold%20875x500.jpg?itok=A0gFmVPT)
By combining 3D printing and dealloying., researchers at LLNL have developed a method for fabricating metal foams with engineered hierarchical architectures consisting of pores at least 3 distinct length scales. LLNL’s method uses direct ink writing (DIW), a 3D printing technique for additive manufacturing to fabricate hierarchical nanoporous metal foams with deterministically controlled 3D…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
Nanomaterials that are emerging out of cutting edge nanotechnology research are a key component for an energy revolution. Carbon-based nanomaterials are ushering in the "new carbon age" with carbon nanotubes, nanoporous carbons, and graphene nanosheets that will prove necessary to provide sustainable energy applications that lessen our dependence on fossil fuels.
Carbon aerogels (CAs)…
![Laser Peening](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Laser%20peening.jpg?itok=l2OKtGme)
LLNL’s system consists of one or more flashlamp-pumped Nd:glass zig-zag amplifiers, a very low threshold stimulated-Brillouin-scattering (SBS) phase conjugator system, and a free-running single frequency Nd:YLF master oscillator.
![Batteryless Sensor](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/batteryless%20sensor.jpg?itok=OiEAlv22)
Chemical and biological sensors based on nanowire or nanotube technologies exhibit observable ultrasensitive detection limits due to their unusually large surface-to-volume architecture. This suggests that nanosensors can provide a distinct advantage over conventional designs. This advantage is further enhanced when the nanosensor can harvest its meager power requirements from the surrounding…
![nuclear reactor](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/nuclear%20reactor.jpg?itok=RMgGfrZv)
The new LLNL technique works by transiently removing and trapping concrete or rock surface material, so that contaminants are confined in a manner that is easy to isolate and remove. Our studies suggest that 10 m2 of surface could be processed per hour. The technique easily scales to more surface/hr.
![energy_absorbing_material.jpg energy_absorbing_material](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/energy_absorbing_material.jpg?itok=UxNZ6nWH)
To overcome limitations with cellular silicone foams, LLNL innovators have developed a new 3D energy absorbing material with tailored/engineered bulk-scale properties. The energy absorbing material has 3D patterned architectures specially designed for specific energy absorbing properties. The combination of LLNL's capabilities in advanced modeling and simulation and the additive…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
LLNL has developed novel nanoporous carbon materials for the surface-stress-induced actuator technology. The morphology of these materials has been designed to combine high surface area and mechanical strength. The process allows for the fabrication of large monolithic pieces with low densities and high structural integrity. One actuation technology relies on electrochemically- induced changes…