LLNL’s researchers use physical vapor deposition (sputter deposition or electron beam deposition) to coat an inert gasket material (i.e. PTFE) with a conductive metal (i.e. copper). The gas diffusion electrode overlaps onto the copper coated gasket to allow for electrical conductivity between the catalyst surface and the flow field/current collector of a CO2 electrolyzer. The coated gasket…

Using their computational design optimization, LLNL researchers have developed copper-based dilute alloy catalysts (contains <10 at.% of the minority metal alloy component) and demonstrated these novel catalysts have improved energy efficiency and selectivity of the methane conversion reaction.  By alloying copper with a small amount of the electropositive minority metal element, the…

Rapid monolith development at scale is achieved through use of a functionally equivalent optic simulant made from a low-cost material to substitute the functional optic. Monolith optical performance is affected not only by thermal expansion but also by temperature inhomogeneity due to the temperature dependence of refractive index.

Aeroptics are a proposed new class of monolithic optical system in aerogel fabricated by molding around a master mandrel. This approach combines the intrinsic stability of proven monolithic telescopes, with the ultralow density of silica aerogels. In Aeroptics, the monolith is hollow with an aerogel substrate providing a supporting structure. Theoretically, Aeroptics could enable 1-m aperture…

This invention achieves both a wider field of view and faster f-number within a monolithic substrate by incorporating an aspheric convex refractive first surface and a planar aspheric field corrector surface on the final refractive surface. These two refractive surfaces work in conjunction with a concave aspheric primary and convex aspheric secondary mirror (e.g. Cassegrain type) to improve…

LLNL’s innovation offers an alternate synthetic route to graphite at lower cost using a molten salt mixture of CaCl2-CaCO3-CaO.  The synthetic production of graphite and other high-value carbon materials is accomplished in molten salt media via electrochemical reduction and transformation of the carbon from the carbonate ion. The broad electrochemical window of molten salts enables the…

The novel LLNL approach is to use projection microstereolithography (LAPµSL), starting with a photocurable methacrylate resin formulation consisting of a combination of a photoinitiator, photoabsorber, inhibitor, solvents, and other additives.  Prior to use, the resin is pretreated to control viscosity for easier handling.  The resin is fed to a LAPµSL printer which employs a near UV light…

The inventors have developed a 3% Yttria partially-stabilized Zirconia (3YZ) ceramic ink that produces parts with both nano and microporosity and is compatible with two AM techniques: DIW and projection microstereolithography (PμSL). The 3YZ nano-porous ceramic printed parts had engineered macro cavities measuring several millimeters in length, wall thicknesses ranging from 200 to 540 μm, and…

This invention describes a multiple nozzle microfluidic unit that allows simultaneous generation streams of multiple layered coaxial liquid jets. Liquids are pumped into the device at a combined flow rate from 100 mL/hr to 10 L/hr. Droplets are created with diameters in the range of 1 µm to 5 mm and can be created with 1-2 shell layers encapsulating fluid. Droplets created from the system can…

Monolithic Telescopes are a novel implementation of a solid catadioptric design form, instantiated in a monolithic block of fused silica.

LLNL is developing the Space-based Telescopes for Actionable Refinement of Ephemeris (STARE). STARE is a constellation of low cost nano-satellites (less than 5Kg) in low-earth orbit dedicated to the observation of space debris in conjunction with a ground-based infrastructure for maintenance, coordination and data processing. Each nano-satellite in the constellation is capable of recording an…