LLNL researchers have developed a method to enhance the performance of polyelectrolyte membranes by using a humidity-controlled crosslinking process which can be applied to precisely adjust the water channels of the membrane.
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![The addition of initiator affects the crossover point of the storage modulus (solid line) and the loss modulus (dashed lined), which indicates curing. As initiator content increases, the reaction proceeds more quickly.](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/Curing%20polysiloxanes.png?itok=5-KLxrp2)
The approach is to use peroxides to modify the reaction kinetics in the production of polysiloxanes. A radical initiator in the presence of a hydride-terminated polysiloxane will increase the rate of curing and reduce manufacturing costs. At a minimum a formulation would contain a hydride-terminated polysiloxane, a platinum catalyst, and an initiator that generates radicals. The content of…
![3D MEA device prior to actuation. A) A completed device. B) Close-up image of a single cell culture well. The large dark metal features at the top and bottom of each cell culture well are ground electrodes, which are all electrically shorted to each other. C) Light micrograph of a single 3DMEA post-actuation. The hinge regions are plastically deformed and allow the probes to stand upright without additional supports.](/sites/default/files/styles/scale_exact_400x400_/public/2023-04/3D_MEA_device.png?itok=5ltXynKC)
To replicate the physiology and functionality of tissues and organs, LLNL has developed an in vitro device that contains 3D MEAs made from flexible polymeric probes with multiple electrodes along the body of each probe. At the end of each probe body is a specially designed hinge that allows the probe to transition from lying flat to a more upright position when actuated and then…
![Second skin smart protection mechanism of responsive nanotube membranes against environmental threats](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/Second%20Skin%20with%20high%20breathability.png?itok=YhZHST7k)
LLNL researchers have developed an alternative route to protective breathable membranes called Second Skin technology, which has transformative potential for protective garments. These membranes are expected to be particularly effective in mitigating physiological burden.
For additional information see article in Advanced Materials “Ultrabreathable and Protective Membranes with Sub-5…