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Small-angle X-ray scattering (SAXS) data of crosslinked polyelectrolyte membrane films formed under different equilibrium humidity conditions

LLNL researchers have developed a method to enhance the performance of polyelectrolyte membranes by using a humidity-controlled crosslinking process which can be applied to precisely adjust the water channels of the membrane.

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The addition of initiator affects the crossover point of the storage modulus (solid line) and the loss modulus (dashed lined), which indicates curing. As initiator content increases, the reaction proceeds more quickly.

The approach is to use peroxides to modify the reaction kinetics in the production of polysiloxanes.  A radical initiator in the presence of a hydride-terminated polysiloxane will increase the rate of curing and reduce manufacturing costs.  At a minimum a formulation would contain a hydride-terminated polysiloxane, a platinum catalyst, and an initiator that generates radicals.  The content of…

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Second skin smart protection mechanism of responsive nanotube membranes against environmental threats

LLNL researchers have developed an alternative route to protective breathable membranes called Second Skin technology, which has transformative potential for protective garments. These membranes are expected to be particularly effective in mitigating physiological burden.

For additional information see article in Advanced Materials “Ultrabreathable and Protective Membranes with Sub-5…