Powder atomic layer deposition process is used to coat nanopowders of host materials (e.g. yttrium aluminum garnet) with optically active neodymium organometal precursor followed by O2/O3 RF plasma to convert to a single layer of Nd2O3. The process can be repeated to build arbitrarily thick layers with custom doping profiles and followed by post-…
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![Picture of SLA printed structures using 3D printable nitrile-containing photopolymer resins](/sites/default/files/styles/scale_exact_400x400_/public/2024-04/SLA%20printed%20structures%20using%203D%20printable%20nitrile-containing%20photopolymer%20resins.jpg?itok=cVxxoNNY)
LLNL’s invention is a photopolymerizable polymer resin that consists of one or more nitrile-functional based polymers. The resin is formulated for SLA based 3D printing allowing for the production of nitrile-containing polymer components that can then be thermally processed into a conductive, highly graphitic materials. The novelty of the invention lies in (1) the photo-curable nitrile-…
![Picture of interlocked electrode structure with metal plated surfaces](/sites/default/files/styles/scale_exact_400x400_/public/2024-03/Interlocked%20electrode%20structure%20with%20metal%20plated%20surfaces.jpg?itok=1A_mLJdP)
LLNL researchers have developed a fabrication process for creating 3D random interdigitated architectures of anodes and cathodes, eliminating the need for a membrane to separate them. This approach is similar to the repeating interdigitated multi-electrode architectures that also were developed at LLNL.
![Diffuse discharge circuit breaker with latching switch](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/Diffuse%20discharge%20circuit%20breaker.png?itok=qWpciEtY)
A thyristor will stay conducting until the current through the device is zero (“current zero”) or perhaps slightly negative. LLNL’s approach is to use the opticondistor (“OTV”) to force this current zero in order to force the device into an “off” state. By combining a light-activated thyristor with an OTV, a noise-immune, high efficiency, high-power switching device can be constructed. The…
![Laser peening induces deep compressive stress, which significantly extends the service lifetime over any conventional treatment](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/laser%20peening%20inducing%20deep%20compressive%20stress.png?itok=oMzDBpkP)
This invention proposes using a pulse laser configured to generate laser pulses and a controller for controlling operation of the pulse laser. The controller is further configured to control the pulse laser to cause the pulse laser to generate at least one of the laser pulses with a spatiotemporally varying laser fluence over a duration of at least one of the laser pulses. The spatiotemporally…
![Printed TPMS membrane structures using nanoporous photoresist](/sites/default/files/styles/scale_exact_400x400_/public/2023-12/Printed%20TPMS%20membrane%20structures.png?itok=siH1EwC9)
LLNL researchers have developed novel advanced manufactured biomimetic 3D-TPMS (triply periodic minimal surface) membrane architectures such as a 3D gyroid membrane. The membrane is printed using LLNL's nano-porous photoresist technology. LLNL’s 3D-TPMS membranes consist of two independent but interpenetrating macropore flow channel systems that are separated by a thin nano-porous wall. 3D-…
![LLNL energy grid protection device](/sites/default/files/styles/scale_exact_400x400_/public/2023-10/LLNL%20energy%20grid%20protection%20device_0.png?itok=vpqzRY_R)
The approach is to leverage the fact that a momentary “load” equal to the power transmission line impedance, (Z0), during the transient can suppress its propagation. Z(0) is typically a fixed impedance of several hundred ohms based on the geometry of most single wire transmission lines.
So, an isolated self-powered opticondistor (OTV) system may provide an ultrafast method of…
![Boss Circuit Breaker](/sites/default/files/styles/scale_exact_400x400_/public/2023-09/Boss%20Circuit%20Breaker.png?itok=7XJ44vZ0)
LLNL’s novel approach to enable MVDC power systems to operate safely is to develop a wideband gap bulk optical semiconductor switch (WBG BOSS) circuit breaker. For higher power, efficiency and temperature operation, vanadium-doped silicon carbide (V-doped SiC) appears to be the most promising basis for WBG BOSS circuit breaker (other dopants like aluminum, boron and nitrogen may further…
![Sub-device integrated with Main device of the flow battery (A) and a cross-section of the sub-device (B)](/sites/default/files/styles/scale_exact_400x400_/public/2023-09/Sub-device%20for%20flow%20battery.png?itok=72VMgGtP)
LLNL researchers has developed an approach to mitigate HER on the ‘plating’ electrode, which uses a sub-device as a rebalancing cell to restore electrolyte properties, including pH, conductivity, and capacity across the main device of the flow battery. This sub-device, which may need to be powered externally, has three major physical components: (1) a cathode electrode, (2) an anode electrode…
![Electrical grid](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/electricaGrid875x500px.jpg?itok=vKB8x1kB)
LLNL has developed a novel methodology for using commercially available automated sensors and actuators which can be deployed at scale in large appliances and plug-in EVs to provide as needed electric grid stabilization capabilities. The approach comprises of a population of voltage relays with a range of setpoints that would gradually reduce load as voltage falls. More severe voltage…
![Electrodeposition of Zn onto 3D printed copper nanowire (CuNW)](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/ElectrodepositionofZnon3dprintedCuNW.jpg?itok=2G2D1kt9)
Improving the active material of the Zn anode is critical to improving the practicality of Zn-MnO2 battery technology. LLNL researchers have developed a new category of 3D structured Zn anode using a direct-ink writing (DIW) printing process to create innovative hierarchical architectures. The DIW ink, which is a gel-based mixture composed of zinc metal powder and organic binders, is extruded…
![Compared with conventional slurry-based film electrode manufacturing methods, dry laser powder bed fusion is promising in generating structured electrodes for high power, low cost lithium ion batteries](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/conventional%20vs%20laser%20PBF%20for%20electrodes.jpg?itok=4KG4KLlE)
To address many of the aforementioned challenges of manufacturing LIBs and SSBs, LLNL researchers have developed a number of inventions that offer proposed solutions for their components:
![New class of lattice-based substrates](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/lattice-based%20substrate.png?itok=vFuqTT03)
To get the best of both worlds – the sensitivity of LC-MS with the speed of PS-MS – and a functional substrate that can maintain sample integrity, LLNL researchers looked to 3D printing. They have patented a novel approach to create lattice spray substrates for direct ionization mass spectroscopy using 3D-printing processes.
![3D Printing of High Viscosity Reinforced Silicone Elastomers](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/3dPrintableSiliconeInks.png?itok=C6lgLCTy)
LLNL researchers, through careful control over the chemistry, network formation, and crosslink density of the ink formulations as well as introduction of selected additives, have been successful in preparing 3D printable silicone inks with tunable material properties. For DIW (direct in writing) applications, LLNL has a growing IP portfolio around 3D printable silicone feedstocks for diverse…
![3D Printing of Fiber Reinforced Composite Thermoset Structures](/sites/default/files/styles/scale_exact_400x400_/public/2023-04/3D%20Printing%20of%20FRC.png?itok=WZfsZPZy)
LLNL’s method of 3D printing fiber-reinforced composites has two enabling features:
![creation of ultra-high energy density matter by an intense laser pulse](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/laser_update875.jpg?itok=793sEzmU)
![Laser Peening](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Laser%20peening.jpg?itok=l2OKtGme)
LLNL’s system consists of one or more flashlamp-pumped Nd:glass zig-zag amplifiers, a very low threshold stimulated-Brillouin-scattering (SBS) phase conjugator system, and a free-running single frequency Nd:YLF master oscillator.
![nuclear reactor](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/nuclear%20reactor.jpg?itok=RMgGfrZv)
The new LLNL technique works by transiently removing and trapping concrete or rock surface material, so that contaminants are confined in a manner that is easy to isolate and remove. Our studies suggest that 10 m2 of surface could be processed per hour. The technique easily scales to more surface/hr.
![Electromechanical battery](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Electromechanical%20battery.jpg?itok=vgNlfBIu)
The design calculations that have been performed in exploring the potentialities of LLNL's new approaches to flywheel energy storage have been built on existing and past LLNL flywheel programs, including a program aimed at flywheel systems for the bulk storage of electricity at utility scale. To achieve the requirements of such systems, as mentioned above, LLNL has developed some key new…