Global energy production, storage and transport are both essential and environmentally impactful. New energy sources, managing and capturing the biproducts of energy expenditure, and repurposing of carbon dioxide are issues of national and global importance. Researchers at LLNL continue to broadly invent novel technologies that intersect at materials, mechanical, electrical, biological and chemical interfaces. Inventions in this portfolio range from bioreactors, to materials, to batteries, motors and new systems.
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Leaders from Lawrence Livermore National Laboratory (LLNL) and the Korea Advanced Institute of Science and Technology (KAIST) recently signed a memorandum of understanding (MOU), as they seek to expand collaborations related to their shared research interests in hydrogen and other low-carbon energy technology.
The two institutions have engaged in informal collaborations since 2018, sharing their knowledge via joint workshops on topics such as hydrogen storage and purification. In addition, experts from both institutions have produced multiple joint publications describing their hydrogen-related research. Other joint activities include a recent study exploring catalytic activity in electrochemical carbon dioxide conversion to products such as carbon monoxide and ethanol.
Lawrence Livermore National Laboratory (LLNL) researchers continue to capture key Department of Energy (DOE) Technology Commercialization Fund (TCF) grants with three new project grants announced in 2024.
This year’s TCF program support projects related to seismology, carbon dioxide removal and using simulations to create clean jet engines.
Coupling electrochemical conversion of the greenhouse gas CO2 with renewable electricity sources — such as solar and wind — promises green production of high-demand chemicals and transportation fuels. Carbon dioxide coupling products such as ethylene, ethanol and acetic acid are particularly useful as feedstocks for the chemical industry and powering vehicles.
To tackle this challenge, Lawrence Livermore National Laboratory (LLNL) and collaborators have developed a catalyst coating platform that used physical vapor deposition (PVD), which offers precise control over thickness, composition, morphology and porosity. The team includes researchers from the University of Delaware, Washington University and the University of Pennsylvania and industry partner Twelve Benefits Corporation
LLNL researchers have developed a self-supporting structural material that promises more efficient carbon capture specifically from air, but generally from all CO2 containing gas sources. The material is produced with a liquid high-amine-content precursor polymer that is functionalized by adding on polymerizable end groups.
This invention solves a limitation in the current practice of adding hydroxyl functional groups to the aminopolymer through the use of an alternative synthetic approach. The novelty of our approach is to produce new structurally modified relatives of common aminopolymers (PEI and PPI) as well as new functionalized materials in which the hydroxyl groups are tethered to a carbon in the backbone…
A thyristor will stay conducting until the current through the device is zero (“current zero”) or perhaps slightly negative. LLNL’s approach is to use the opticondistor (“OTV”) to force this current zero in order to force the device into an “off” state. By combining a light-activated thyristor with an OTV, a noise-immune, high efficiency, high-power switching device can be…
The approach is to leverage the fact that a momentary “load” equal to the power transmission line impedance, (Z0), during the transient can suppress its propagation. Z(0) is typically a fixed impedance of several hundred ohms based on the geometry of most single wire transmission lines.
So, an isolated self-powered opticondistor (OTV) system may provide an ultrafast method of…
LLNL’s novel approach to enable MVDC power systems to operate safely is to develop a wideband gap bulk optical semiconductor switch (WBG BOSS) circuit breaker. For higher power, efficiency and temperature operation, vanadium-doped silicon carbide (V-doped SiC) appears to be the most promising basis for WBG BOSS circuit breaker (other dopants like aluminum, boron and nitrogen may further…
LLNL researchers has developed an approach to mitigate HER on the ‘plating’ electrode, which uses a sub-device as a rebalancing cell to restore electrolyte properties, including pH, conductivity, and capacity across the main device of the flow battery. This sub-device, which may need to be powered externally, has three major physical components: (1) a cathode electrode, (2) an anode…
LLNL has developed a novel methodology for using commercially available automated sensors and actuators which can be deployed at scale in large appliances and plug-in EVs to provide as needed electric grid stabilization capabilities. The approach comprises of a population of voltage relays with a range of setpoints that would gradually reduce load as voltage falls. More severe voltage…
Improving the active material of the Zn anode is critical to improving the practicality of Zn-MnO2 battery technology. LLNL researchers have developed a new category of 3D structured Zn anode using a direct-ink writing (DIW) printing process to create innovative hierarchical architectures. The DIW ink, which is a gel-based mixture composed of zinc metal powder and organic binders, is…
To address many of the aforementioned challenges of manufacturing LIBs and SSBs, LLNL researchers have developed a number of inventions that offer proposed solutions for their components:
This invention describes a multiple nozzle microfluidic unit that allows simultaneous generation streams of multiple layered coaxial liquid jets. Liquids are pumped into the device at a combined flow rate from 100 mL/hr to 10 L/hr. Droplets are created with diameters in the range of 1 µm to 5 mm and can be created with 1-2 shell layers encapsulating fluid. Droplets created from the system can…
LLNL has a patented process to produce colloidal silica directly from geothermal fluids. Livermore’s process uses membranes to produce a mono-dispense slurry of colloidal silica particles for which there are several applications. LLNL has demonstrated that colloidal silica solutions that result from extraction of silica from geothermal fluids undergo a transition to a solid gel over a range of…
The design calculations that have been performed in exploring the potentialities of LLNL's new approaches to flywheel energy storage have been built on existing and past LLNL flywheel programs, including a program aimed at flywheel systems for the bulk storage of electricity at utility scale. To achieve the requirements of such systems, as mentioned above, LLNL has developed some key new…