LLNL researchers have developed a TDLAS-based, standalone, real-time gas analyzer in a small form-factor for continuous or single-point monitoring. The system can analyze multiple gases with ultra-high sensitivity (ppm detection levels) in harsh conditions when utilizing wavelength-modulation spectroscopy (WMS).
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![Electrochemical CO2 conversion to valuable fuels and chemicals](/sites/default/files/styles/scale_exact_400x400_/public/2024-03/Electrochemical%20CO2%20conversion%20to%20valuable%20fuels%20and%20chemicals1.png?itok=G20rQOcY)
LLNL’s researchers use physical vapor deposition (sputter deposition or electron beam deposition) to coat an inert gasket material (i.e. PTFE) with a conductive metal (i.e. copper). The gas diffusion electrode overlaps onto the copper coated gasket to allow for electrical conductivity between the catalyst surface and the flow field/current collector of a CO2 electrolyzer. The coated gasket…
![CT Scanner Adobe Stock Image](/sites/default/files/styles/scale_exact_400x400_/public/2024-03/CT%20Scanner.jpeg?itok=tHCxNWpA)
The essence of this invention is a method that couples network architecture using neural implicit representations coupled with a novel parametric motion field to perform limited angle 4D-CT reconstruction of deforming scenes.
![SEM image of nanoporous Cu catalyst material](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/SEM_nanoporous_Cu_catalyst.png?itok=xqwrkv1f)
Using their computational design optimization, LLNL researchers have developed copper-based dilute alloy catalysts (contains <10 at.% of the minority metal alloy component) and demonstrated these novel catalysts have improved energy efficiency and selectivity of the methane conversion reaction. By alloying copper with a small amount of the electropositive minority metal element, the…
![Diffuse discharge circuit breaker with latching switch](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/Diffuse%20discharge%20circuit%20breaker.png?itok=qWpciEtY)
A thyristor will stay conducting until the current through the device is zero (“current zero”) or perhaps slightly negative. LLNL’s approach is to use the opticondistor (“OTV”) to force this current zero in order to force the device into an “off” state. By combining a light-activated thyristor with an OTV, a noise-immune, high efficiency, high-power switching device can be constructed. The…
![A cross-sectional schematic of a diffused Ga2O3 photoconductive semiconductor switch (PCSS)](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/a%20cross-sectional%20schematic%20of%20a%20diffused%20beta-Ga2O3%20PCSS.png?itok=Z41s0FbO)
The researchers’ approach leverages the concept that dopants have high diffusivities in Ga2O3; the key lies in the selection of the appropriate dopant. This LLNL invention describes two device types that employ this design:
![Samples of optimized diamond switches](/sites/default/files/styles/scale_exact_400x400_/public/2024-01/Samples%20of%20optimized%20diamond%20switches.png?itok=5syzdD0q)
Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength.
Characteristics of the LLNL-developed switch are as follows:
![Custom PCB design of a PCSS Laser Diode Driver](/sites/default/files/styles/scale_exact_400x400_/public/2023-11/PCSS%20Laser%20Diode%20Driver.png?itok=WQ2FNHQF)
LLNL researchers have invented an ultrafast PCSS to drive a high-power laser diode with arbitrary pulse widths. These devices operate by supplying a high voltage (>10 kV) to one side of the switch. A short pulse of light illuminates the semiconductor, instantly turning it from highly resistive to highly conductive.
![multi-spectral nondestructive characterization of in-shell tree nuts](/sites/default/files/styles/scale_exact_400x400_/public/2023-11/multi-spectral%20nondestructive%20characterization%20of%20in-shell%20tree%20nuts.png?itok=-W2LFRIH)
LLNL’s novel technology automates the inspection process by using a scanning system that captures data within the walnut shell without having to open the shell. The system output gives a visual image inside the walnut shell sufficient to evaluate and rate the quality of the walnut. The system uses a camara and radar that can capture data at a rapid rate. This improves speed and reliability…
![solid state streak detector](/sites/default/files/styles/scale_exact_400x400_/public/2023-10/Solid%20State%20Streak%20Detector.png?itok=4t6vjY-r)
The approach is to develop a solid-state X-ray imager based on the architecture of the Silicon Drift Detector (SDD) which uses a series of cathode strips on both sides of a silicon wafer to achieve bulk depletion and electron drift. The invention leverages this SDD functionality to achieve signal stretching of liberated charge carriers from X-Ray photons that converts the time domain into the…
![Graphite](/sites/default/files/styles/scale_exact_400x400_/public/2023-09/graphite.jpg?itok=2CQBn1ca)
LLNL’s innovation offers an alternate synthetic route to graphite at lower cost using a molten salt mixture of CaCl2-CaCO3-CaO. The synthetic production of graphite and other high-value carbon materials is accomplished in molten salt media via electrochemical reduction and transformation of the carbon from the carbonate ion. The broad electrochemical window of molten salts enables the…
![National Ignition Facility (NIF)](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/NIF.jpg?itok=Gem1TaQc)
This novel detector for characterizing IFE implosions is an alternative to the current RTNADs to measure neutron fluxes > 3x1011 neutrons/cm2 at high shot rates. The detector consists of a stack of small square metal wafers separated by thin insulating spacers. Every other wafer is held at high voltage while the remaining wafers are grounded. The stack acts as an…
![Schematic of LLNL’s Fast Image Acquisition System](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/Fast%20Image%20Acqusition%20System.png?itok=HFyr-Goi)
LLNL’s novel approach is to use a continuous moving camera with a scan speed of >1 mm/sec and a frame rate of 100 frames per second. The key is to have a light source that flashes with a duration of one nanosecond, thus essentially freezing the image with no blur. Clear images of high resolution can then be captured through a high-magnification objective lens (reflection mode) or through…
![twister oven component with reflective inner cylinder surface](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/twister%20oven%20component.png?itok=v3jlzm2V)
U.S. Patent No. 11,555,965 describes LLNL’s invention of “Illumination Frustums” for photoconductive switches to capture and “frustrate” the light from leaving the frustum. LLNL researcher’s latest novel invention, “Twister Oven”, achieves this by encouraging laser light absorption in a photo conductor material. Light enters the oven twisting and reflecting, making near normal incident multi…
![A photoconductive switch made from a synthetic, chemical vapor deposition diamond under test](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/Photoconductive%20switch.jpg?itok=xC1O7vXg)
Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength. The diamond material is chosen to be doped with substitutional nitrogen to act as a source of electrons. The device architecture allows maximum light entering the aperture. The top and bottom electrodes are made of ultra-wide bandgap (UWBG)…
![3DQ Concept: Use two 2D detectors to enable detection of 3D position for the same event.](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/3DQ%20Concept.png?itok=hPgLZTTl)
LLNL’s approach to the development of a wide-field, three-dimensional quantum (3DQ) microscope is to harness quantum entangled photons to form simultaneous 3D optical images, which could be a new paradigm for 3D volumetric imaging of biological specimens. The 3DQ microscope is comprised of a novel optical system with highly sensitive detectors and an on-demand light source of entangled…
![schematic of LLNL’s field emission photocathode device architecture with examples of tunable SiC surface micro- and nanostructures fabricated at LLNL](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/FE%20photocathode%20device.png?itok=z-1Om9v8)
LLNL researchers faced this challenge by bridging the gap between VEDs and solid-state electronics (SSE). Their approach was to create a hybrid vacuum microelectronic device (VMD) architecture that combines the properties of vacuum as the electronic medium and the compact form factor and manufacturing scalability of semiconductor microelectronic chips.
![Segments of transmission line lengths can be switched to open circuit (as shown) or shorted to the ground (not shown)](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/Segments%20of%20tranmission%20line%20lengths.png?itok=FF0qaBGw)
Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength. The diamond material is specifically doped with substitutional nitrogen, which act as a source of electrons. The device architecture allows maximum light entering the aperture. The top and bottom electrodes are made of ultra wide band gap (UWBG)…
![Annular illumination on photo conductor by Conical Total Internal Reflection “CTIR” endcap](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/CONIFR.png?itok=L4wSanXF)
The approach is to use a custom-designed frustrum and attach it to the optical fiber that connects to the PCSS. Light from the fiber enters the frustrum, spreads out, and enters the PCSS. Any unabsorbed light re-enters the frustrum and, because of its geometry, reflects back into the PCSS itself with only a negligible fraction escaping from the fiber. The shape of the novel frustrum is…
![Projection Microstereolithographic Additively Manufactured Anion Exchange Membrane](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/PuSL%20AEM.png?itok=kMLx_xAK)
The novel LLNL approach is to use projection microstereolithography (LAPµSL), starting with a photocurable methacrylate resin formulation consisting of a combination of a photoinitiator, photoabsorber, inhibitor, solvents, and other additives. Prior to use, the resin is pretreated to control viscosity for easier handling. The resin is fed to a LAPµSL printer which employs a near UV light…
![SEM image showing internal porosity of DIW printed parts](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/internal%20porosity%20of%20DIW%20printed%20parts%20sq.png?itok=_QsLKjM7)
The inventors have developed a 3% Yttria partially-stabilized Zirconia (3YZ) ceramic ink that produces parts with both nano and microporosity and is compatible with two AM techniques: DIW and projection microstereolithography (PμSL). The 3YZ nano-porous ceramic printed parts had engineered macro cavities measuring several millimeters in length, wall thicknesses ranging from 200 to 540 μm, and…
![IPO logo over a face profile with interconnected lines](/sites/default/files/2020-11/IPO_logo_placeholder.jpg)
LLNL’s SAS technology embedded within a facility is developed to sense, detect, localize, alert, and communicate an active shooter(s) to first responders. It relies on three integrated compact sensors that detect sound, infrared light (from the muzzle blast) and vibrations emanating from a gunshot. Fusing the data from these detectors minimizes false alarms.
![IPO logo over a face profile with interconnected lines](/sites/default/files/2020-11/IPO_logo_placeholder.jpg)
The key to time-reversal for an active shooter detection/tracking application is being able to estimate the space-time transfer function (Green’s function) between source-enclosure-receiver. This approach begins with the acoustic mapping of an indoor muzzle blast.
![Microcapsules offer high surface area and a superior delivery system.](/sites/default/files/styles/scale_exact_400x400_/public/2020-11/Figure1IDEA.jpg?itok=9pdFUISw)
This invention describes a multiple nozzle microfluidic unit that allows simultaneous generation streams of multiple layered coaxial liquid jets. Liquids are pumped into the device at a combined flow rate from 100 mL/hr to 10 L/hr. Droplets are created with diameters in the range of 1 µm to 5 mm and can be created with 1-2 shell layers encapsulating fluid. Droplets created from the system can…
![Livermore Tomography Tools LTT](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/LTT.jpg?itok=cQE9Kpef)
To solve these challenges using new and existing CT system designs, LLNL has developed an innovative software package for CT data processing and reconstruction. Livermore Tomography Tools (LTT) is a modern integrated software package that includes all aspects of CT modeling, simulation, reconstruction, and analysis algorithms based on the latest research in the field. LTT contains the most…
![Livermore Tomography Tools LTT](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/LTT.jpg?itok=cQE9Kpef)
LLNL's 3D X-ray imager combines two different hardware pieces. The first is an x-ray optic with a depth-of-field that is small compared to the object under investigation. Reflective Wolter type x-ray optics are one such design. These hollow optics have a relatively large collection efficiency and can be designed with a large field of view. The depth of focus, which is the distance over which a…
![multichannel_pyrometer.jpg multichannel_pyrometer](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/multichannel_pyrometer.jpg?itok=x0sCe_BN)
LLNL researchers have designed and tested performance characteristics for a multichannel pyrometer that works in the NIR from 1200 to 2000 nm. A single datapoint without averaging can be acquired in 14 microseconds (sampling rate of 70,000/s). In conjunction with a diamond anvil cell, the system still works down to about 830K.
![AgAg2S reference electrode](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/AgAg2S%20reference%20electrode.jpg?itok=kL2OzfHy)
LLNL has developed a reference electrode that is a great improvement on the widely used silver or platinum wire QRE commonly used in electrochemistry in ionic liquids. This new reference electrode, based on a silver-sulfide coated silver wire, exhibits greatly improved stability over a QRE. The stability of our RE approaches that of the Ag/Ag+ RE, but unlike the Ag/Ag+ RE, the RE reported here…
![Natalia Zaitseva examines a single crystal growing in a solution-growth crystallizer developed for production of stilbene crystals for fast neutron detection](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/solution-growth%20crystallizer.jpg?itok=SlXZs_1s)
LLNL researchers have grown and characterized scintillator crystals of Strontium Iodide (SrI2). Scintillator energy resolution and light yield proportionality surpass NaI and are similar to LaBr3. The SrI2 scintillators doped with europium (Eu) exhibit very high light yields (> 100,000 photons/MeV), extremely good energy resolution (<3% at 662 keV) and excellent light yield…
![Radiation Sign](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Radiation%20Sign.jpg?itok=_mPjSajQ)
The LLNL detector measures radiation over a large dynamic range, spanning both high hazardous levels and weak levels, including natural background radiation. In weak radiation fields, the detector also measures gamma-ray spectra. The cost of the detector is significantly less than the total cost of existing separate detectors that could perform the same measurements.
![STJ x-ray spectrometer (shown on the table) to characterize a material sample.](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/STJ%20x-ray%20spectrometer.jpg?itok=OEllnuT5)
LLNL's X-ray spectrometers based on STJ have been developed for high-resolution soft X-ray spectroscopy. STJ consist of two superconducting thin film electrodes separated by a thin insulating tunnel barrier. They measure X-ray energies from the increase in tunneling current after X-ray absorption in one of the electrodes excites additional charge carriers above the superconducting energy gap.…
![gemini.jpg gemini](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/gemini.jpg?itok=elYbWcjz)
LLNL has developed a radiation detector that cools to operating temperatures in 1-2 hours using two separate cooling stages. The first cooling brings the instrument to operating temperature. The embedded second cooling system achieves portable detection that can be sustained for 8-12 hours.
In addition, an integrated, hermetically-sealed package has been developed complete with…
![Natalia Zaitseva examines a single crystal growing in a solution-growth crystallizer developed for production of stilbene crystals for fast neutron detection](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/solution-growth%20crystallizer.jpg?itok=SlXZs_1s)
LLNL has identified solution-grown organic crystals having scintillation efficiency not only close to, but even exceeding that of stilbene.. LLNL's invention relates to a new class of neutron detectors based on scintillation response of organic single crystals. More specifically, the use of organic molecules grown from solution and to molecules including the basic benzene or phenyl structure…
![Truck approaching radiation portal monitor](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Truck%20approaching%20radiation%20portal%20monitor.jpg?itok=gULQckpn)
LLNL scientists have developed an approach for full spectrum analysis during gamma ray spectrometry using a spectral library signature created from a large amount of spectral data. The signature can be compared to unknown spectral measurements for the identification of previously unknown nuclear material.
![plastic_scintillators.jpg plastic_scintillators](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/plastic_scintillators.jpg?itok=_aZx24vp)
Scientists at Lawrence Livermore National Laboratory have developed a plastic that can detect neutrons, something previously thought impossible.
Livermore scientists demonstrated a plastic scintillator that can discriminate between neutrons and gamma rays with a polyvinyltoluene (PVT) polymer matrix loaded with a scintillating dye, 2,5-diphenyloxazole (PPO). They have found that…
![Radio Active Materials processed](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Radio%20Active%20Materials%20processed_0.jpg?itok=ESogQosQ)
The invention utilizes the statistical nature of radiation transport as well as modern processing techniques to implement a physics-based, sequential statistical processor. By this we mean that instead of accumulating a pulse-height spectrum as is done in many other systems, each photon is processed individually upon arrival and then discarded. As each photon arrives, a decision is…
![Marine helmet](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Marine%20helmet-inside.jpg?itok=8W_dqpgI)
LLNL's high fidelity hydrocode is capable of predicting blast loads and directly coupling those loads to structures to predict a mechanical response. By combining this code and our expertise in modeling blast-structure interaction and damage, along with our access to experimental data and testing facilities, we can contribute to the design of protective equipment that can better mitigate the…
![Next generation pillar detector](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/next-generation%20pillar%20detector.jpg?itok=7NBEyiYS)
LLNL's neutron "Pillar Detector" fabrication technology uses semiconductor-based micro-structured elements as an electrical signal generation medium for the detection of neutrons. These materials in the form of semiconductor "pillars" embedded in matrix of high cross-section neutron converter materials (such as Boron) that emit charged particles upon interaction with neutrons. These charged…
![Transparent Scintillators](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Transparent%20Scintillators.jpg?itok=YDhoI0XA)
Transparent ceramic fabrication allows the production of gadolinium- , lutetium-, and terbium-based garnets which are difficult to grow by melt techniques due to phase instabilities. Phase stabilization of the garnets is accomplished by the addition of the intersubstitutional ions, Gallium and/or Scandium.
Scientists have developed many versatile and scaleable fabrication methods.…