LLNL researchers have developed a method to enhance the performance of polyelectrolyte membranes by using a humidity-controlled crosslinking process which can be applied to precisely adjust the water channels of the membrane.
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![Examples of different UV exposure patterns printed from the same multi-material resin. Darker yellow regions have higher UV exposure times leading to tougher regions.](/sites/default/files/styles/scale_exact_400x400_/public/2024-01/UV%20exposure%20patterns.jpg?itok=gxDjP8_E)
LLNL researchers have developed an innovative and uniform single-pot polymer multi-material system, based on a combination of 3 different reactive chemistries. By combining the three different constituent monomers, fine control of mechanical attributes, such as elastic modulus, can be achieved by adjusting the dosage of UV light throughout the additive manufacturing process. This results in…
![Top down view of a Gas phase synthesized graphene (GSG) UV curable polymer composite film.](/sites/default/files/styles/scale_exact_400x400_/public/2024-01/GSG%20UV%20curable%20polymer%20composite%20film.jpg?itok=9K-LMcLo)
LLNL researchers have developed a method to incorporate gas phase synthesized graphene (GSG) as a unique additive in a UV-crosslinkable polymer formulation. The GSG is added by using a planetary mixer to obtain a homogenous suspension of GSG in polymer. The resulting formulation is highly stable and doesn't show signs of phase separation or solid sedimentation. The polymer formulation is then…
![OALV design with High-k Photoconductor and High-k Optical Window](/sites/default/files/styles/scale_exact_400x400_/public/2024-01/OALV%20design.png?itok=xMV74hXb)
LLNL researchers has developed designs to augment WBG/UWBG-based OALVs to improve their power handling capability under CW operational environments. These designs include:
![SEM image of tantalum airbridges](/sites/default/files/styles/scale_exact_400x400_/public/2023-12/SEM%20image%20of%20tantalum%20airbridges.png?itok=ZSZvL90K)
LLNL researchers developed a novel method to nucleate the alpha phase of Tantalum on a polymer surface at room temperature, allowing for the controllable formation of a variety of 3D structures, such as airbridges. Using this method with a subsequent Piranha etch results in the complete removal of the residues of the polymer 'scaffolding' or template while allowing the deposited tantalum…
![Powder in Chemical Watch Glass](/sites/default/files/styles/scale_exact_400x400_/public/2023-12/gray%20powder.jpeg?itok=u_5ZtG7H)
LLNL researchers have developed a Li-Sn-Zn ternary alloy and its method of production. Instead of traditional alloying techniques, the alloy was synthesized using mechanical alloying (high energy ball milling). With high purity elemental powders of lithium, tin and zinc, LLNL researchers were able to prepare Li60Sn20Zn20 as well as Li70Sn20Zn10 nanopowders.
![Scanning electron microscopy image of carbonized resorcinol-formaldehyde formulation.](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/SEM%20image%20of%20carbonized%20resorcinol-formaldehyde%20formulation.png?itok=46D5k1qt)
LLNL inventors have created innovative steps in the synthesis, carbonation and activation steps of aerogel manufacturing that allows for large scale production. These steps are:
1. Synthesis: a novel pre-cure step with subsequent gelation (RF precursor solution is heated with stirring to achieve a mixed liquid intermediate temperature, the precursor solution is then allowed to cool,…
![Livermore researchers support efforts to limit the need for rare-earth elements in U.S. clean-energy technologies.](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/Reducing%20Reliance%20on%20Critical%20Materials.png?itok=IuC6bH4r)
CMI—a DOE Energy Innovation Hub—is a public/private partnership led by the Ames Laboratory that brings together the best and brightest research minds from universities, national laboratories (including LLNL), and the private sector to find innovative technology solutions to make better use of materials critical to the success of clean energy technologies as well as develop resilient and secure…
![A sample of micro-architectured graphene aerogel, made from one of the lightest materials on Earth, sits atop a flower.](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/micro-architectured%20graphene%20aerogel.jpg?itok=t56kL59Q)
To overcome challenges that existing techniques for creating 3DGs face, LLNL researchers have developed a method that uses a light-based 3D printing process to rapidly create 3DG lattices of essentially any desired structure with graphene strut microstructure having pore sizes on the order of 10 nm. This flexible technique enables printing 3D micro-architected graphene objects with complex,…
![One embodiment of a solid-state lithium-air battery based on gyroid foams.](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/Li-Air%20Battery%20Gyroid%20Foam.jpg?itok=gPAwVj0O)
LLNL researchers have developed a new 3D printable lithium-air battery that uses a novel thin solid state ceramic electrolyte. LLNL’s invention overcomes the combined challenges of low power density and low cycle life in previously designed lithium-air batteries by using solid state electrolytes to achieve stability and multiscale structuring of the electrolyte to achieve low interfacial…
![Biosorption-based REE recovery and Sc extraction from low-grade feedstocks.](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/Biosorption-based%20Sc%20separation.png?itok=nULPXLYl)
The novel technology developed at LLNL is a new, effective means of separating and concentrating Sc from lanthanides and non-REEs in unconventional, waste-derived feedstocks, thereby transforming an essentially valueless solution into valuable Sc concentrates. The results represent an important advance in the development of an environmentally sustainable alternative to organic solvent-based…
![natural protein lanmodulin, LanM (blue) bound to three REE ions (cyan).](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/LanMwithREEions.png?itok=UcejC0kj)
LLNL researchers along with collaborators at Pennsylvania State University have found that a newly discovered natural protein named Lanmodulin (LanM) could be a potential candidate for extracting REEs from ore or other sources such as coal ash as well as purifying the REE material. Through joint research, the scientists found that LanM undergoes a large conformational change in response to…
![Segments of transmission line lengths can be switched to open circuit (as shown) or shorted to the ground (not shown)](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/Segments%20of%20tranmission%20line%20lengths.png?itok=FF0qaBGw)
Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength. The diamond material is specifically doped with substitutional nitrogen, which act as a source of electrons. The device architecture allows maximum light entering the aperture. The top and bottom electrodes are made of ultra wide band gap (UWBG)…
![Annular illumination on photo conductor by Conical Total Internal Reflection “CTIR” endcap](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/CONIFR.png?itok=L4wSanXF)
The approach is to use a custom-designed frustrum and attach it to the optical fiber that connects to the PCSS. Light from the fiber enters the frustrum, spreads out, and enters the PCSS. Any unabsorbed light re-enters the frustrum and, because of its geometry, reflects back into the PCSS itself with only a negligible fraction escaping from the fiber. The shape of the novel frustrum is…
![IPO logo over a face profile with interconnected lines](/sites/default/files/2020-11/IPO_logo_placeholder.jpg)
LLNL researchers have developed a custom formulated extreme low viscosity reactive silicone resin base modified with a temperature dependent thixotrope along with a modified catalyst package. The uncatalyzed composition is capable of accepting loadings of polymer microspheres sufficient to produce a cured bulk rubber that has a density as low as 0.3 g/cc, thus compatible with high-resolution…
![nanocomposite_aerogel.jpg nanocomposite_aerogel](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/nanocomposite_aerogel.jpg?itok=PuNPrvkg)
Livermore researchers have developed two novel TiCl4 based non-alkoxide sol-gel approaches for the synthesis of SiO2/TiO2 nanocomposite aerogels. Composite SiO2-TiO2 aerogels were obtained by epoxide-assisted gelation (EAG route) of TiCl4/DMF solution in the presence SiO2 aerogel particles. Additionally, the same TiCl4/DMF solution was employed to prepare SiO2@TiO2 aerogels by a facile one-…
![freeze_casting_porous_materials](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/freeze_casting_porous_materials.png?itok=2twOT_K3)
The LLNL method is based on freeze‐casting of aerosolized and pressurized metal salt solutions and subsequent thermal processing. This method generates both porous particles with sizes down to one micron and macroscopic monoliths with nanometer scale ligaments/struts. The material's density can be controlled during the freeze‐dried stage. Compared to conventional approaches, this method…
![CNT Carbon Nanotube yarns support spherical](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/CNT%20yarns%20support%20spherical.jpg?itok=ndieUaDs)
LLNL has developed a liquid-free method that increases the overall mechanical resistance of self-supported, carbon nanotube assemblies through nanoscale reinforcement by gas-phase deposition of a thermally cross-linkable polymer. Polymer-reinforcement increases the strength of CNT yarns after crosslinking. For example, a minimal amount (<200 nm) of poly-glycidyl metacrylate (PGMA) deposited…
![Bio-Based Shape Memory Polymer](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Bio-Based%20Shape%20Memory%20Polymer.png?itok=LD-aph8l)
LLNL researchers have developed a novel method of 3D printing regular microstructured architectures and subsequent complex macrostructures from additively manufactured bio-based composite thermoset shape memory polymer composite materials. This technology for 3D additively manufactured parts utilizes up to a 4 axis control DIW system for fabricating bio based thermally cured epoxy based SMP…
![composite_material](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/composite_material1.jpg?itok=fS_as8eL)
LLNL researchers have developed the hardware and chemistry to allow additive manufacturing of short carbon fibers in a thermoset polymer matrix which have a high degree of structural alignment over conventional cast or pressed short/chopped carbon fiber polymer composites.
The invention is based on the shear dispersal, alignment and concentration of fiber fraction within a resin…
![Spectroscopic Injection Pulser prototype](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Spectroscopic%20Injection%20Pulser%20prototype%20.jpg?itok=CQZmEGas)
The technology that is available has the capability to inject realistic radiation detection spectra into the amplifier of a radiation detector and produce the all the observables that are available with that radiation detection instrument; count-rate, spectrum, dose rate, etc.
The system uses the capability of LLNL to generate the source output for virtually any source and determine…
![Batteryless Sensor](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/batteryless%20sensor.jpg?itok=OiEAlv22)
Chemical and biological sensors based on nanowire or nanotube technologies exhibit observable ultrasensitive detection limits due to their unusually large surface-to-volume architecture. This suggests that nanosensors can provide a distinct advantage over conventional designs. This advantage is further enhanced when the nanosensor can harvest its meager power requirements from the surrounding…
![metallic_nanospheres.jpg metallic_nanospheres](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/metallic_nanospheres.jpg?itok=-j4nK6vi)
The nanosphere synthesis process works when a nanostructured substrate is heated above a critical temperature in the presence of a small amount of metal on the nanostructured surface. The metal acts as a particular type of catalyst for nanowire formation. It is periodically segregated within the nanowire in a thermodynamically well-defined process as nanowires grow. The result is…
![OTV Image](/sites/default/files/styles/scale_exact_400x400_/public/2022-02/OTV%20Image.png?itok=KEAmHqpM)
The Optical Transconductance Varistor (OTV, formerly Opticondistor) overcomes depletion region voltage limitations by optically exciting wide bandgap materials in a compact package. A 100μm thick crystal could have the capability approaching 40kV and would replace numerous equivalent junction devices. Thus, unlike present junction transistors or diodes, this wide bandgap device can be stacked…
![plants Lattice](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/plantsLattice2_875x500px.jpg?itok=3ArsXjAU)
Redox ion-exchange polymers ("redox-ionites") and membranes possessing cation- and anion- exchange, amphoteric, complex-forming and oxidation-reduction abilities have been developed on the basis of the biocompatible synthetic and chemically modified natural polymers. In addition, developments have been made towards methods of obtaining of water-soluble and spatially cross-linked ionites of…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
Nanomaterials that are emerging out of cutting edge nanotechnology research are a key component for an energy revolution. Carbon-based nanomaterials are ushering in the "new carbon age" with carbon nanotubes, nanoporous carbons, and graphene nanosheets that will prove necessary to provide sustainable energy applications that lessen our dependence on fossil fuels.
Carbon aerogels (CAs)…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
LLNL has developed novel nanoporous carbon materials for the surface-stress-induced actuator technology. The morphology of these materials has been designed to combine high surface area and mechanical strength. The process allows for the fabrication of large monolithic pieces with low densities and high structural integrity. One actuation technology relies on electrochemically- induced changes…