LLNL researchers have developed a method to enhance the performance of polyelectrolyte membranes by using a humidity-controlled crosslinking process which can be applied to precisely adjust the water channels of the membrane.
Keywords
- Show all (208)
- Instrumentation (39)
- Additive Manufacturing (37)
- Sensors (16)
- Synthesis and Processing (16)
- Diagnostics (13)
- Photoconductive Semiconductor Switches (PCSS) (9)
- Imaging Systems (8)
- 3D Printing (7)
- Carbon Utilization (6)
- Semiconductors (6)
- Compact Space Telescopes (5)
- Data Science (5)
- Laser Materials Processing (5)
- Therapeutics (5)
- Cybersecurity (4)
- Diode Lasers (4)
- Material Design (4)
- (-) Electric Grid (8)
- (-) Materials for Energy Products (7)
- (-) Optical Switches (4)
![Diffuse discharge circuit breaker with latching switch](/sites/default/files/styles/scale_exact_400x400_/public/2024-02/Diffuse%20discharge%20circuit%20breaker.png?itok=qWpciEtY)
A thyristor will stay conducting until the current through the device is zero (“current zero”) or perhaps slightly negative. LLNL’s approach is to use the opticondistor (“OTV”) to force this current zero in order to force the device into an “off” state. By combining a light-activated thyristor with an OTV, a noise-immune, high efficiency, high-power switching device can be constructed. The…
![OALV design with High-k Photoconductor and High-k Optical Window](/sites/default/files/styles/scale_exact_400x400_/public/2024-01/OALV%20design.png?itok=xMV74hXb)
LLNL researchers has developed designs to augment WBG/UWBG-based OALVs to improve their power handling capability under CW operational environments. These designs include:
![LLNL energy grid protection device](/sites/default/files/styles/scale_exact_400x400_/public/2023-10/LLNL%20energy%20grid%20protection%20device_0.png?itok=vpqzRY_R)
The approach is to leverage the fact that a momentary “load” equal to the power transmission line impedance, (Z0), during the transient can suppress its propagation. Z(0) is typically a fixed impedance of several hundred ohms based on the geometry of most single wire transmission lines.
So, an isolated self-powered opticondistor (OTV) system may provide an ultrafast method of…
![Boss Circuit Breaker](/sites/default/files/styles/scale_exact_400x400_/public/2023-09/Boss%20Circuit%20Breaker.png?itok=7XJ44vZ0)
LLNL’s novel approach to enable MVDC power systems to operate safely is to develop a wideband gap bulk optical semiconductor switch (WBG BOSS) circuit breaker. For higher power, efficiency and temperature operation, vanadium-doped silicon carbide (V-doped SiC) appears to be the most promising basis for WBG BOSS circuit breaker (other dopants like aluminum, boron and nitrogen may further…
![Sub-device integrated with Main device of the flow battery (A) and a cross-section of the sub-device (B)](/sites/default/files/styles/scale_exact_400x400_/public/2023-09/Sub-device%20for%20flow%20battery.png?itok=72VMgGtP)
LLNL researchers has developed an approach to mitigate HER on the ‘plating’ electrode, which uses a sub-device as a rebalancing cell to restore electrolyte properties, including pH, conductivity, and capacity across the main device of the flow battery. This sub-device, which may need to be powered externally, has three major physical components: (1) a cathode electrode, (2) an anode electrode…
![Electrical grid](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/electricaGrid875x500px.jpg?itok=vKB8x1kB)
LLNL has developed a novel methodology for using commercially available automated sensors and actuators which can be deployed at scale in large appliances and plug-in EVs to provide as needed electric grid stabilization capabilities. The approach comprises of a population of voltage relays with a range of setpoints that would gradually reduce load as voltage falls. More severe voltage…
![Electrodeposition of Zn onto 3D printed copper nanowire (CuNW)](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/ElectrodepositionofZnon3dprintedCuNW.jpg?itok=2G2D1kt9)
Improving the active material of the Zn anode is critical to improving the practicality of Zn-MnO2 battery technology. LLNL researchers have developed a new category of 3D structured Zn anode using a direct-ink writing (DIW) printing process to create innovative hierarchical architectures. The DIW ink, which is a gel-based mixture composed of zinc metal powder and organic binders, is extruded…
![Livermore researchers support efforts to limit the need for rare-earth elements in U.S. clean-energy technologies.](/sites/default/files/styles/scale_exact_400x400_/public/2023-07/Reducing%20Reliance%20on%20Critical%20Materials.png?itok=IuC6bH4r)
CMI—a DOE Energy Innovation Hub—is a public/private partnership led by the Ames Laboratory that brings together the best and brightest research minds from universities, national laboratories (including LLNL), and the private sector to find innovative technology solutions to make better use of materials critical to the success of clean energy technologies as well as develop resilient and secure…
![Compared with conventional slurry-based film electrode manufacturing methods, dry laser powder bed fusion is promising in generating structured electrodes for high power, low cost lithium ion batteries](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/conventional%20vs%20laser%20PBF%20for%20electrodes.jpg?itok=4KG4KLlE)
To address many of the aforementioned challenges of manufacturing LIBs and SSBs, LLNL researchers have developed a number of inventions that offer proposed solutions for their components:
![One embodiment of a solid-state lithium-air battery based on gyroid foams.](/sites/default/files/styles/scale_exact_400x400_/public/2023-06/Li-Air%20Battery%20Gyroid%20Foam.jpg?itok=gPAwVj0O)
LLNL researchers have developed a new 3D printable lithium-air battery that uses a novel thin solid state ceramic electrolyte. LLNL’s invention overcomes the combined challenges of low power density and low cycle life in previously designed lithium-air batteries by using solid state electrolytes to achieve stability and multiscale structuring of the electrolyte to achieve low interfacial…
![Segments of transmission line lengths can be switched to open circuit (as shown) or shorted to the ground (not shown)](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/Segments%20of%20tranmission%20line%20lengths.png?itok=FF0qaBGw)
Design and construction of a photoconductive switch requires a diamond photoconductor illuminated by light of a certain excitation wavelength. The diamond material is specifically doped with substitutional nitrogen, which act as a source of electrons. The device architecture allows maximum light entering the aperture. The top and bottom electrodes are made of ultra wide band gap (UWBG)…
![Annular illumination on photo conductor by Conical Total Internal Reflection “CTIR” endcap](/sites/default/files/styles/scale_exact_400x400_/public/2023-05/CONIFR.png?itok=L4wSanXF)
The approach is to use a custom-designed frustrum and attach it to the optical fiber that connects to the PCSS. Light from the fiber enters the frustrum, spreads out, and enters the PCSS. Any unabsorbed light re-enters the frustrum and, because of its geometry, reflects back into the PCSS itself with only a negligible fraction escaping from the fiber. The shape of the novel frustrum is…
![nanocomposite_aerogel.jpg nanocomposite_aerogel](/sites/default/files/styles/scale_exact_400x400_/public/2019-08/nanocomposite_aerogel.jpg?itok=PuNPrvkg)
Livermore researchers have developed two novel TiCl4 based non-alkoxide sol-gel approaches for the synthesis of SiO2/TiO2 nanocomposite aerogels. Composite SiO2-TiO2 aerogels were obtained by epoxide-assisted gelation (EAG route) of TiCl4/DMF solution in the presence SiO2 aerogel particles. Additionally, the same TiCl4/DMF solution was employed to prepare SiO2@TiO2 aerogels by a facile one-…
![AgAg2S reference electrode](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/AgAg2S%20reference%20electrode.jpg?itok=kL2OzfHy)
LLNL has developed a reference electrode that is a great improvement on the widely used silver or platinum wire QRE commonly used in electrochemistry in ionic liquids. This new reference electrode, based on a silver-sulfide coated silver wire, exhibits greatly improved stability over a QRE. The stability of our RE approaches that of the Ag/Ag+ RE, but unlike the Ag/Ag+ RE, the RE reported here…
![Electromechanical battery](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/Electromechanical%20battery.jpg?itok=vgNlfBIu)
The design calculations that have been performed in exploring the potentialities of LLNL's new approaches to flywheel energy storage have been built on existing and past LLNL flywheel programs, including a program aimed at flywheel systems for the bulk storage of electricity at utility scale. To achieve the requirements of such systems, as mentioned above, LLNL has developed some key new…
![OTV Image](/sites/default/files/styles/scale_exact_400x400_/public/2022-02/OTV%20Image.png?itok=KEAmHqpM)
The Optical Transconductance Varistor (OTV, formerly Opticondistor) overcomes depletion region voltage limitations by optically exciting wide bandgap materials in a compact package. A 100μm thick crystal could have the capability approaching 40kV and would replace numerous equivalent junction devices. Thus, unlike present junction transistors or diodes, this wide bandgap device can be stacked…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
Nanomaterials that are emerging out of cutting edge nanotechnology research are a key component for an energy revolution. Carbon-based nanomaterials are ushering in the "new carbon age" with carbon nanotubes, nanoporous carbons, and graphene nanosheets that will prove necessary to provide sustainable energy applications that lessen our dependence on fossil fuels.
Carbon aerogels (CAs)…
![Batteryless Sensor](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/batteryless%20sensor.jpg?itok=OiEAlv22)
Chemical and biological sensors based on nanowire or nanotube technologies exhibit observable ultrasensitive detection limits due to their unusually large surface-to-volume architecture. This suggests that nanosensors can provide a distinct advantage over conventional designs. This advantage is further enhanced when the nanosensor can harvest its meager power requirements from the surrounding…
![3D printed electrodes](/sites/default/files/styles/scale_exact_400x400_/public/2022-06/3D%20printed%20electrodes.jpg?itok=HPvcODM8)
LLNL has developed novel nanoporous carbon materials for the surface-stress-induced actuator technology. The morphology of these materials has been designed to combine high surface area and mechanical strength. The process allows for the fabrication of large monolithic pieces with low densities and high structural integrity. One actuation technology relies on electrochemically- induced changes…