Global energy production, storage and transport are both essential and environmentally impactful. New energy sources, managing and capturing the biproducts of energy expenditure, and repurposing of carbon dioxide are issues of national and global importance. Researchers at LLNL continue to broadly invent novel technologies that intersect at materials, mechanical, electrical, biological and chemical interfaces. Inventions in this portfolio range from bioreactors, to materials, to batteries, motors and new systems.
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The trade journal R&D World Magazine recently announced the winners of the awards, often called the “Oscars of innovation,” recognizing new commercial products, technologies and materials that are available for sale or license for their technological significance.
Lawrence Livermore National Laboratory (LLNL) scientists and engineers have earned four awards among the top 100 inventions worldwide. With this year’s results, the Laboratory has now collected a total of 186 R&D 100 awards since 1978.
Submitted through LLNL’s Innovation and Partnerships Office (IPO), these awards recognize the impact that Livermore innovation, in collaboration with industry partners, can have on the U.S. economy as well as globally.
A multidisciplinary team of researchers at Lawrence Livermore National Laboratory (LLNL) developed a new type of electrically controlled, near-infrared smart window that can cut near-infrared light transmission by almost 50%. Their secret ingredient? Vertically aligned carbon nanotubes—tiny, tube-shaped structures made from carbon atoms that are thousands of times thinner than a human hair. The research was published in Nano Letters.
Information about the opportunity to license the technology can be found here: Electrochromic Devices Made from VACNTs
LLNL and Verne have demonstrated a novel pathway for creating high-density hydrogen through a research program funded by Department of Energy’s ARPA-E. The demonstration validated that it is possible to efficiently reach cryo-compressed hydrogen conditions with liquid hydrogen-like density directly from a source of gaseous hydrogen.
Verne began working with LLNL in 2021 through a Strategic Partnership Project to test Verne’s tanks at LLNL’s cryogenic hydrogen fueling facility. Collaborations progressed through two Cooperative Research and Development Agreements in 2023-24 facilitated by LLNL’s Innovation and Partnerships Office (IPO).
LLNL inventors have developed a gas diffusion electrode (GDE) architecture employing a multi-stack design. The first layer consists of a physical vapor deposited metallic catalyst film which then has a second composite layer deposited on top consisting of a second catalyst material mixed with a polymer electrolytes. The two layers working in tandem allow for near 100% CO…
LLNL’s researchers use physical vapor deposition (sputter deposition or electron beam deposition) to coat an inert gasket material (i.e. PTFE) with a conductive metal (i.e. copper). The gas diffusion electrode overlaps onto the copper coated gasket to allow for electrical conductivity between the catalyst surface and the flow field/current collector of a CO2 electrolyzer. The coated gasket…
Using their computational design optimization, LLNL researchers have developed copper-based dilute alloy catalysts (contains <10 at.% of the minority metal alloy component) and demonstrated these novel catalysts have improved energy efficiency and selectivity of the methane conversion reaction. By alloying copper with a small amount of the electropositive minority metal element, the…
A thyristor will stay conducting until the current through the device is zero (“current zero”) or perhaps slightly negative. LLNL’s approach is to use the opticondistor (“OTV”) to force this current zero in order to force the device into an “off” state. By combining a light-activated thyristor with an OTV, a noise-immune, high efficiency, high-power switching device can be…
The approach is to leverage the fact that a momentary “load” equal to the power transmission line impedance, (Z0), during the transient can suppress its propagation. Z(0) is typically a fixed impedance of several hundred ohms based on the geometry of most single wire transmission lines.
So, an isolated self-powered opticondistor (OTV) system may provide an ultrafast method of…
LLNL’s novel approach to enable MVDC power systems to operate safely is to develop a wideband gap bulk optical semiconductor switch (WBG BOSS) circuit breaker. For higher power, efficiency and temperature operation, vanadium-doped silicon carbide (V-doped SiC) appears to be the most promising basis for WBG BOSS circuit breaker (other dopants like aluminum, boron and nitrogen may further…
LLNL researchers has developed an approach to mitigate HER on the ‘plating’ electrode, which uses a sub-device as a rebalancing cell to restore electrolyte properties, including pH, conductivity, and capacity across the main device of the flow battery. This sub-device, which may need to be powered externally, has three major physical components: (1) a cathode electrode, (2) an anode…
LLNL’s innovation offers an alternate synthetic route to graphite at lower cost using a molten salt mixture of CaCl2-CaCO3-CaO. The synthetic production of graphite and other high-value carbon materials is accomplished in molten salt media via electrochemical reduction and transformation of the carbon from the carbonate ion. The broad electrochemical window of molten salts enables the…
LLNL has developed a novel methodology for using commercially available automated sensors and actuators which can be deployed at scale in large appliances and plug-in EVs to provide as needed electric grid stabilization capabilities. The approach comprises of a population of voltage relays with a range of setpoints that would gradually reduce load as voltage falls. More severe voltage…
Improving the active material of the Zn anode is critical to improving the practicality of Zn-MnO2 battery technology. LLNL researchers have developed a new category of 3D structured Zn anode using a direct-ink writing (DIW) printing process to create innovative hierarchical architectures. The DIW ink, which is a gel-based mixture composed of zinc metal powder and organic binders, is…
To address many of the aforementioned challenges of manufacturing LIBs and SSBs, LLNL researchers have developed a number of inventions that offer proposed solutions for their components:
The novel LLNL approach is to use projection microstereolithography (LAPµSL), starting with a photocurable methacrylate resin formulation consisting of a combination of a photoinitiator, photoabsorber, inhibitor, solvents, and other additives. Prior to use, the resin is pretreated to control viscosity for easier handling. The resin is fed to a LAPµSL printer which employs a near UV…
The inventors have developed a 3% Yttria partially-stabilized Zirconia (3YZ) ceramic ink that produces parts with both nano and microporosity and is compatible with two AM techniques: DIW and projection microstereolithography (PμSL). The 3YZ nano-porous ceramic printed parts had engineered macro cavities measuring several millimeters in length, wall thicknesses ranging from 200 to 540 μm, and…
This invention describes a multiple nozzle microfluidic unit that allows simultaneous generation streams of multiple layered coaxial liquid jets. Liquids are pumped into the device at a combined flow rate from 100 mL/hr to 10 L/hr. Droplets are created with diameters in the range of 1 µm to 5 mm and can be created with 1-2 shell layers encapsulating fluid. Droplets created from the system can…