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Schematic of six-ring design for IL-13352

This LLNL invention proposes a new microstructured large mode area fiber design that enhances the confinement of the core mode while strongly suppressing thermal or scattering mediated dynamic couplings with higher order modes thought to be responsible for generating undesirable Transverse Mode Instabilities. The design accomplishes higher order mode suppression and core mode confinement by…

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Schematic showing how laser can be used to induce localized heating

LLNL researchers developed a novel strategy that involves material transformations such as oxidation, nitridation, or carbonization. In one embodiment, copper is heated under ambient conditions resulting in its surface being oxidized and turned into copper oxide, where a new material (e.g., copper oxide) is developed via transformation (e.g., oxidation) without additional addition deposition…

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Comparative photos of LLNL metal oxide nanoparticle (MONPs) loaded optical adhesive formulations vs commercial offerings using the same MONPs (~1 mm thick films).

LLNL researchers have created a suitably compliant adhesive that is based on a thiol monomer mixed with an epoxy monomer in the presence of metal oxide nanoparticles.  When cured into films or pucks, the adhesives are optically transparent with a RI up to ~1.68 at 532 nm with varying shore A hardness in the range of 50 to 98. The adhesive can potentially be mixed and potted between Ti:…

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Photograph of glass sample unplated on one side (left) and plated with nickel phosphorous on the other (right)

LLNL researchers have continued to develop their pioneering DIW 3D-printed glass optics technology that allows for the 3D printing of single- and multi-material optical glass compositions in complex shapes. This LLNL invention further proposes incorporating dopants (including, but not limited to TiO2 and Pd) into slurries and inks for 3D printing of glass components that can then be directly…

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Process Flow for making the gas diffusion electrode

LLNL researchers have developed a novel method of making a GDE that starts with a porous, conductive structural framework made from metallic materials which standalone would be too hydrophilic and macroporous.

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Standing in LLNL’s Center for Micro Nano Technology, Nathan Ray holds a marvel of optical engineering, a 5-centimeter metasurface optic

This LLNL invention concerns a method for patterning the index of refraction by fabricating a spatially invariant metasurface, and then apply spatially varied mechanical loading to compress the metasurface features vertically and spread them radially. In doing so, the index of refraction can be re-written on the metasurface, thus enabling index patterning. This process allows rapid 'rewriting…

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IR transparent composite foam covering a roof’s surface allow for passive cooling at night as well as daytime

LLNL researchers have developed a passive cooling system which is (1) infrared transparent in the 8-13 um wavelength range, (2) optically reflective to reduce surface heating from sunlight, and (3) thermally insulating to avoid heating from surrounding air. The device uses a material composite that provides cooling via maintaining a temperature difference between a surface and ambient air…

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A hypothetical structure-optimized adsorbent packing with hierarchical pores and submicron features will facilitate mass transfer to adsorption sites. SEM image of porous fluoropolymer

LLNL researchers have developed a self-supporting structural material that promises more efficient carbon capture specifically from air, but generally from all CO2 containing gas sources. The material is produced with a liquid high-amine-content precursor polymer that is functionalized by adding on polymerizable end groups.

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Flash Stock Image

This invention proposes achieving the same effect of a single, high intensity pulse through the use of a closely spaced burst of short duration pulses. By keeping the intensity of the individual pulses below the damage threshold the risk of catastrophic damage is greatly mitigated. Additionally, the pulses are directed to strike the target at locations temporally and spatially sufficiently…

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Colorized illustration from a simulation of a holographic plasma lens. The red concentric circles denote alternating high- and low-density plasma rings. The blue dot at the center represents the focused light. Image by Matthew Edwards/LLNL

Holography fully encodes a 3D light field by imprinting its interference pattern with a reference laser beam in a nonlinear medium. By crossing two pump laser pulses in a gas jet, a hologram can be recorded as a distribution of plasma, allowing manipulation of a subsequent high-intensity probe beam. The interference between two collinear beams with distinct foci produces a plasma zone plate, a…

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Left to right: Drew Willard, Brendan Reagan, and Issa Tamer work on the Tm:YLF laser system. Photos by Jason Laurea

This invention proposes the use of a nonlinear spectral broadening subsystem as a post-CPA pulse compression add-on for high energy laser systems. The proposed solution utilizes the beam profile of a high peak power laser as a reference to shape a highly transmissive nonlinear plastic (e.g., CR39) itself to ensure a spatially homogeneous nonlinear spectral broadening.

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structures created using method for producing laser gain media by atomic layer deposition

Powder atomic layer deposition process is used to coat nanopowders of host materials (e.g. yttrium aluminum garnet) with optically active neodymium organometal precursor followed by O2/O3 RF plasma to convert to a single layer of Nd2O3. The process can be repeated to build arbitrarily thick layers with custom doping profiles and followed by post-…

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SEM image of etched metasurface with angled features

This novel invention specifically enables the fabrication of arbitrarily tailored birefringence characteristics in nano-structured meta-surfaces on non-birefringent substrates (e.g. fused silica). The birefringent nano-structured meta-surface is produced by angled directional reactive ion beam etching through a nano-particle mask. This method enables the simultaneous tailoring of refractive…

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Schematic of one methodology for achieving a thicker substrate engraved meta-surface (SEMS) layer

This invention (US Patent No. 11,294,103) is an extension of another LLNL invention, US Patent No. 10,612,145, which utilizes a thin sacrificial metal mask layer deposited on a dielectric substrate (e.g. fused silica) and subsequently nanostructured through a laser generated selective thermal de-wetting process.

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Schematic for Polarization Manipulation of Free-Space Electromagnetic Radiation Fields

This invention proposes fabrication of a sandwich of two or more (typically 3) magneto-rheologically finished (MRF’d) birefringent plates with purpose designed arbitrary surface contour profiles and eigen-axis orientation. The tailored surface contour profiles are designed to compensate for the observed de-polarization characteristics of a particular solid-state laser operating in a particular…

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Stock image of 3d render of network made of wind turbines, solar panels, battery and house

LLNL researchers have designed and produced, both conductive and non-conductive porous electrode components manufactured for improved metal deposition, discharging, and fluid dynamics in hybrid flow batteries.  This is achieved through Direct Ink Writing (DIW) additive manufacturing.  The engineered 3D electrodes enable uniform current distribution and even metal deposition during…

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HAPLS

This LLNL invention is an optical amplifier, wherein the gain element is in the form of a frustum and a spherically diverging laser beam is introduced into the gain medium via the small face of the frustum. In one embodiment, the pump beam is generated by one or more chromium-lasers that are counter-propagating, having been introduced through the large face of the frustum. The gain medium may…

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Small-angle X-ray scattering (SAXS) data of crosslinked polyelectrolyte membrane films formed under different equilibrium humidity conditions

LLNL researchers have developed a method to enhance the performance of polyelectrolyte membranes by using a humidity-controlled crosslinking process which can be applied to precisely adjust the water channels of the membrane.

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Adobe stock vibration wave

This invention circumvents the GMAPD deadtime limitation by using an array of GMAPDs in a non-imaging configuration instead of a single element. By using an array, with sufficient number of elements, guarantees there is always at least one element available to detect an incoming photon even if others are in the deadtime zone.

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Electronic Wave

This invention works by imaging an ultrafast pulse diffracted from a large grating onto a spatial light modulator (SLM) thereby directly transcribing an arbitrary record on a pulse front tilted (PFT) ultrafast pulse. The grating generates PFT of the input pulse, and the SLM provides temporal control of the pulse through the space-to-time mapping of the tilted pulse. Coupling this patterned…

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Electrochemical CO2 conversion to valuable fuels and chemicals

LLNL’s researchers use physical vapor deposition (sputter deposition or electron beam deposition) to coat an inert gasket material (i.e. PTFE) with a conductive metal (i.e. copper). The gas diffusion electrode overlaps onto the copper coated gasket to allow for electrical conductivity between the catalyst surface and the flow field/current collector of a CO2 electrolyzer. The coated gasket…

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Water being decontaminated via photocatalysis

LLNL researchers have developed a method for enhancing the photocatalytic degradation of organic contaminants in water through the incorporation of patterned plasmonic metal nanostructures with TiO2 photocatalysts. The multi-step process to incorporate UV plasmonic metal nanostructures with the photocatalyst can be briefly summarized below:
•    Nanosphere lithography…

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Flue Gas Emissions a Major Source of Atmospheric CO2

This invention solves a limitation in the current practice of adding hydroxyl functional groups to the aminopolymer through the use of an alternative synthetic approach. The novelty of our approach is to produce new structurally modified relatives of common aminopolymers (PEI and PPI) as well as new functionalized materials in which the hydroxyl groups are tethered to a carbon in the backbone…

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Picture of interlocked electrode structure with metal plated surfaces

LLNL researchers have developed a fabrication process for creating 3D random interdigitated architectures of anodes and cathodes, eliminating the need for a membrane to separate them.  This approach is similar to the repeating interdigitated multi-electrode architectures that also were developed at LLNL. 

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Electronic Wave

This invention exploits the non-linearities of optical Mach-Zehnder (MZ) electrooptic modulators to enhance small signal dynamic range at higher bandwidths. A linear photodiode (PD) converts the amplified optical signal output from the MZ back to an electrical signal completing an Electrical-Optical-Electrical (EOE) conversion cycle. The dynamic range can be further enhanced by daisy chaining…

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Schematic of a plasma-grating-based laser system using a double-CPA architecture

This invention draws on the higher damage tolerance of plasma to manipulate high-intensity light. Plasma is a difficult medium to control and sets stringent limits on optical performance. A compact high-power laser system can be realized using plasma transmission gratings for chirped pulse compression based on currently achievable plasma properties and minimal plasma volume. A double…

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Schematic of ionization grating

This invention proposes a volumetric transmission grating based on ionization created in a neutral gas by crossing and interfering two short-pulse pump lasers so that their intensity maxima rise above the medium’s ionization threshold. This will create a modulated index of refraction that can diffract a subsequent probe beam like a transmission grating. Crucially for the application of…

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SEM image of nanoporous Cu catalyst material

Using their computational design optimization, LLNL researchers have developed copper-based dilute alloy catalysts (contains <10 at.% of the minority metal alloy component) and demonstrated these novel catalysts have improved energy efficiency and selectivity of the methane conversion reaction.  By alloying copper with a small amount of the electropositive minority metal element, the…

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LLNL designed Triboelectric Device architecture

The two primary methods for actuating triboelectric (mechanical/friction) devices are contact separation and lateral sliding.  Rather than an air gap to separate the contacts and sliding, LLNL researchers have conceived of a flexible, self-contained triboelectric device that can be compressed.  The key to the invention is the dual function of a flexible, compressive material that…

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Diffuse discharge circuit breaker with latching switch

A thyristor will stay conducting until the current through the device is zero (“current zero”) or perhaps slightly negative.  LLNL’s approach is to use the opticondistor (“OTV”) to force this current zero in order to force the device into an “off” state.  By combining a light-activated thyristor with an OTV, a noise-immune, high efficiency, high-power switching device can be…

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Laser peening induces deep compressive stress, which significantly extends the service lifetime over any conventional treatment

This invention proposes using a pulse laser configured to generate laser pulses and a controller for controlling operation of the pulse laser. The controller is further configured to control the pulse laser to cause the pulse laser to generate at least one of the laser pulses with a spatiotemporally varying laser fluence over a duration of at least one of the laser pulses. The spatiotemporally…

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MonoTel Compact Monolithic Space Telescope

Rapid monolith development at scale is achieved through use of a functionally equivalent optic simulant made from a low-cost material to substitute the functional optic. Monolith optical performance is affected not only by thermal expansion but also by temperature inhomogeneity due to the temperature dependence of refractive index.

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MonoTel Compact Monolithic Space Telescope

Aeroptics are a proposed new class of monolithic optical system in aerogel fabricated by molding around a master mandrel. This approach combines the intrinsic stability of proven monolithic telescopes, with the ultralow density of silica aerogels. In Aeroptics, the monolith is hollow with an aerogel substrate providing a supporting structure. Theoretically, Aeroptics could enable 1-m aperture…

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Adobe Stock image laser beam

This invention proposes to engineer the current density along the length of a laser diode to overcome the penalty associated with non-uniformity resulting from asymmetry in the gain, photon or carrier density despite having uniform contact. Optimizing the current density profile enables diode lasers to operate with greater power conversion efficiency or operate with equivalent power conversion…

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Schematic showing mismatched coefficient of thermal expansion (CTE) coating

This invention proposes to engineer the temperature dependence of the emission wavelength of LEDs and laser diodes. The approach is to use a strain-inducing coating to counteract the intrinsic temperature coefficient of the emission wavelength of the LED or laser diode device thereby rendering it athermal. This invention avoids additional complexity, size, weight and power dissipation of…

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Photoconductive Semiconductor Laser Diodes and LEDs

This invention proposes a method to overcome the key limitation of electrically pumped lasers based on AlN, AlGaN, or AlInGaN, namely the lack of suitable shallow donor and acceptor dopants. As the band gap of these materials increases (and the emission wavelength decreases), both electrons and holes require greater thermal energies in order to ionize.

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Adobe Stock image laser beam

Laser diode lensing effect can be substantially reduced by creating a pattern interface such that the substrate is only attached at the diode mesa. This is achieved by either creating a pattern solder joint and/or pattern substrate.

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NIF Lasers

This invention configures multiple spherical substrate targets to roll independently of one another.  The spheres’ rolling motion is deliberately randomized to promote uniform coating while eliminating the interaction (rubbing, sliding) of adjacent spheres that is present in conventional sphere coating designs. The devices’ novel structure features enable the collimation of depositing…

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large potassium dihydrogen phosphate KDP crystal

This invention takes advantage of the high water-solubility of key NIF KDP crystal optics and uses water as an etchant to remove surface defects and improve the laser induced damage threshold. Since pure water etches KDP too fast, this invention is to disperse water as nanosized droplets in a water-in-oil micro-emulsion. While in a stable micro-emulsion form, the surfactant additives prevent…

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LLNL’s CO2 laser-based Optics Mitigation Facility adapted for controlled laser melting of glass optics.

This invention proposes to use laser induced melting/softening to locally reshape the form of a glass optic. The local glass densification that results induces predictable stresses that through plate deformation mechanics yield a deterministic methodology for arbitrarily reshaping an optic surface figure and wavefront without the need to remove material.

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MonoTel Compact Monolithic Space Telescope

This invention achieves both a wider field of view and faster f-number within a monolithic substrate by incorporating an aspheric convex refractive first surface and a planar aspheric field corrector surface on the final refractive surface. These two refractive surfaces work in conjunction with a concave aspheric primary and convex aspheric secondary mirror (e.g. Cassegrain type) to improve…

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Thin disc of a transparent ceramic

This invention is about a Material Jetting technique used to form a ceramic green body that is subsequently processed into a transparent ceramic optic with unique tunable spatial control of the composition as a function of position only achievable via additive manufacturing methods. This method uses ceramic particles loaded into a liquid slurry with required viscosity and surface tension to be…

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Scanning electron micrograph of scalable, grating-like nanoscale metal mask (line period ~35 nm)

This invention consists of a method of forming nanoscale metal lines to produce a grating-like mask with wide area coverage over the surface of a durable optical material such as fused silica. Subsequent etching processes transfer the metal mask to the underlying substrate forming a birefringent metasurface. This method enables the production of ultrathin waveplates for high power laser…

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Laser Beam Shaping to Improve 3D Printing. Credit: Veronica Chen/LLNL

This LLNL invention proposes a novel approach to spectral interferometry, the preferred technique for characterizing nanosecond long records of laser pulse shapes with femtosecond resolution. Linear techniques are much more sensitive than the many nonlinear techniques of the prior art and can be used for very weak pulses. However, they depend on being able to interfere the signal with a well…

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optical element

LLNL has designed and demonstrated a novel transmission Spectral Beam Combining grating optic assembly with megawatt power handling capabilities. The design consists of a monolithic structure with an input transform optic and an output transmission grating. The design features LLNL’s proven compact, lightweight Spectral Channels Splicer architecture to combine adjacent spectral channels of…

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Scanning electron micrograph of bulk metamaterial structures fabricated at LLNL

Heat sensitive materials such as piezoelectric and MEMS devices and assemblies, magnetic sensors, nonlinear optical crystals, laser glass or solid-state laser materials, etc. cannot be exposed to excess temperatures which in the context of this invention, means materials that cannot be exposed to temperatures greater than 50°C (122°F). LLNL’s invention describes a low-temperature method of…

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Powder in Chemical Watch Glass

LLNL researchers have developed a Li-Sn-Zn ternary alloy and its method of production.  Instead of traditional alloying techniques, the alloy was synthesized using mechanical alloying (high energy ball milling).  With high purity elemental powders of lithium, tin and zinc, LLNL researchers were able to prepare Li60Sn20Zn20 as well as Li70Sn20Zn10 nanopowders.

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A gas separation membrane containing the optimized molten hydroxide solution held in a porous material selectively turns CO2 into carbonates, which are transported across the membrane by diffusion. Water—as steam—on the sweep (right) side is critical for recovering the captured carbon for storage by converting the carbonate back into CO2.

Facing these challenges, LLNL researchers focused on ceramic material as it is inherently inert and developed a host of inventions where porous ceramic membranes are prepared using a sacrificial polymer template. By controlling polymer/ceramic nanoparticle ratio and processing conditions, the pore morphology of the ceramic itself is controlled and optimized for the various applications. The…

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Emissions Stock Image

The heart of this LLNL invention lies in combining existing concepts for absorber intercooling and packing geometry into a novel configuration that yields the benefits of in-line intercooling at reduced capital cost and equipment size. The technology utilizes LLNL-developed Triply Periodic Minimal Surface (TPMS) structures (US Patent No. 11,389,765) that are produced using additive…

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SEM image showing the morphology of a 3D printed porous carbon substrate with well distributed cobalt particles in cross section

LLNL researchers have developed novel catalytic electrodes for energy storage applications from inexpensive starting materials.  The LLNL team are using a group of 3D printing inks that contain precursors of earth-abundant catalysts (e.g. Ni, Co and Fe compounds); the catalytic materials are imbedded into the ink matrix.  To carefully control the properties such as surface area and…

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Images and topology scans of (top row) cold sprayed LLZO (lithium lanthanum zirconium tantalum oxide) and (bottom row) cold sprayed NMC (lithium nickel manganese cobalt oxide) on top of LLZTO

LLNL has co-developed a number of technologies thatuse cold spray deposition that enable new designs for functional materials with low waste.

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Skin-layered Microporous Separators for Li-Ion Batteries

LLNL’s novel approach is to use separators based on a bilayer structure that consists of a self-formed skin layer on a microporous membrane.  The highly porous membrane is made of 1,6-hexanediol diacrylate (HDDA), which provides high Li ion conductivity.  The skin layer is relatively dense that allows for easy Li-ion transport but can effectively block undesired constituents such as…

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LLNL energy grid protection device

The approach is to leverage the fact that a momentary “load” equal to the power transmission line impedance, (Z0), during the transient can suppress its propagation.  Z(0) is typically a fixed impedance of several hundred ohms based on the geometry of most single wire transmission lines.

So, an isolated self-powered opticondistor (OTV) system may provide an ultrafast method of…

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JFET Device Structure

LLNL’s novel approach is to use diamond substrates with the desired donor (nitrogen) and acceptor (boron) impurities.   In order to optically activate these deep impurities, the invention requires at least one externally or internally integrated light source.  The initial exposure to light can set up the desired conduction current, after which the light source could be turned…

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Simulation of ion selectivity related to pore size in flow through electrode.

LLNL researchers have developed a novel technique of flow-through electrode capacitive deioinization (FTE-CDI) which can be tailored for selective ion removal from water. It uses porous carbon aerogel materials as capacitive deionization (CDI) electrodes to selectively remove scale forming divalent ions (e.g., magnesium, calcium) from "hard" waters.

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Schematic outlining how diamond anvils are used for synthesis of novel compounds using only applied pressure

LLNL inventors have devised a solely pressure-based method for producing Li3P and Na3P using a diamond anvil cell at room temperature. By applying relatively low pressure (<1GPa) to elemental mixtures of lithium / phosphorous and sodium / phosphorous and LLNL researchers were able to synthesize lithium- and sodium-rich phosphorous compounds (Li3P and Na3P), respectively. 

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Boss Circuit Breaker

LLNL’s novel approach to enable MVDC power systems to operate safely is to develop a wideband gap bulk optical semiconductor switch (WBG BOSS) circuit breaker.  For higher power, efficiency and temperature operation, vanadium-doped silicon carbide (V-doped SiC) appears to be the most promising basis for WBG BOSS circuit breaker (other dopants like aluminum, boron and nitrogen may further…

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Sub-device integrated with Main device of the flow battery (A) and a cross-section of the sub-device (B)

LLNL researchers has developed an approach to mitigate HER on the ‘plating’ electrode, which uses a sub-device as a rebalancing cell to restore electrolyte properties, including pH, conductivity, and capacity across the main device of the flow battery.  This sub-device, which may need to be powered externally, has three major physical components: (1) a cathode electrode, (2) an anode…

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Graphite

LLNL’s innovation offers an alternate synthetic route to graphite at lower cost using a molten salt mixture of CaCl2-CaCO3-CaO.  The synthetic production of graphite and other high-value carbon materials is accomplished in molten salt media via electrochemical reduction and transformation of the carbon from the carbonate ion. The broad electrochemical window of molten salts enables the…

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HAPLS

LLNL researchers have developed a high average power Faraday rotator that is gas-cooled and uniquely designed to dissipate heat uniformly so that it does not build up in the optical component and affect its performance.  The Faraday rotator material is sliced into smaller disks like a loaf of bread so that high speed helium gas can flow between the slices.  With this highly efficient…

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Electrical grid

LLNL has developed a novel methodology for using commercially available automated sensors and actuators which can be deployed at scale in large appliances and plug-in EVs to provide as needed electric grid stabilization capabilities. The approach comprises of a population of voltage relays with a range of setpoints that would gradually reduce load as voltage falls. More severe voltage…

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Electrodeposition of Zn onto 3D printed copper nanowire (CuNW)

Improving the active material of the Zn anode is critical to improving the practicality of Zn-MnO2 battery technology. LLNL researchers have developed a new category of 3D structured Zn anode using a direct-ink writing (DIW) printing process to create innovative hierarchical architectures.  The DIW ink, which is a gel-based mixture composed of zinc metal powder and organic binders, is…

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An example of interdigitated beam-based lattice design

The approach developed by LLNL researchers is to use computer-aided design and advanced manufacturing methods to fabricate two or more continuous electrode structures intertwining in 3D space.  This configuration provides improved control electric field uniformity and the ability to carry out multiple electrochemical reactions.  This invention utilizes design tools to create…

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Livermore researchers support efforts to limit the need for rare-earth elements in U.S. clean-energy technologies.

CMI—a DOE Energy Innovation Hub—is a public/private partnership led by the Ames Laboratory that brings together the best and brightest research minds from universities, national laboratories (including LLNL), and the private sector to find innovative technology solutions to make better use of materials critical to the success of clean energy technologies as well as develop resilient and secure…

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National Ignition Facility (NIF)

This novel detector for characterizing IFE implosions is an alternative to the current RTNADs to measure neutron fluxes > 3x1011 neutrons/cm2 at high shot rates. The detector consists of a stack of small square metal wafers separated by thin insulating spacers. Every other wafer is held at high voltage while the remaining wafers are grounded. The stack acts as an…

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Compared with conventional slurry-based film electrode manufacturing methods, dry laser powder bed fusion is promising in generating structured electrodes for high power, low cost lithium ion batteries

To address many of the aforementioned challenges of manufacturing LIBs and SSBs, LLNL researchers have developed a number of inventions that offer proposed solutions for their components:

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One embodiment of a solid-state lithium-air battery based on gyroid foams.

LLNL researchers have developed a new 3D printable lithium-air battery that uses a novel thin solid state ceramic electrolyte.   LLNL’s invention overcomes the combined challenges of low power density and low cycle life in previously designed lithium-air batteries by using solid state electrolytes to achieve stability and multiscale structuring of the electrolyte to achieve low…

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The High-Repetition-Rate Advanced Petawatt Laser System (HAPLS), the world’s most advanced and highest average power diode-pumped petawatt laser system, at LLNL.

This invention discloses a method to minimize transient variations in the wavelength- and/or pointing-behavior of an optic, without requiring a reduction in its thermal resistance, optical absorption, or operating irradiance. The invention employs a combination of a time-varying heat source and time-varying thermal resistance and/or heat sink temperature to achieve temperature stability of the…

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Linearly polarized light entering a half-wave plate can be resolved into two waves, parallel and perpendicular to the optic axis of the waveplate ("Waveplate" by Bob Mellish is licensed under CC BY-SA 3.0).

This novel method of producing waveplates from isotropic optical materials (e.g. fused silica) consists of forming a void-dash metasurface using the following process steps:

IPO logo over a face profile with interconnected lines

This technology can replace combustion heat with renewable energy in the form of electricity from variable renewable energy (VRE), such as photovoltaic (PV) solar and clean hydrogen (H2). Granular media functions as a heat-storage medium that enables renewable energy to be time-shifted from when it is available to when it is needed by an industrial process. The heated granular media, as the…

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Projection Microstereolithographic Additively Manufactured Anion Exchange Membrane

The novel LLNL approach is to use projection microstereolithography (LAPµSL), starting with a photocurable methacrylate resin formulation consisting of a combination of a photoinitiator, photoabsorber, inhibitor, solvents, and other additives.  Prior to use, the resin is pretreated to control viscosity for easier handling.  The resin is fed to a LAPµSL printer which employs a near UV…

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SEM image showing internal porosity of DIW printed parts

The inventors have developed a 3% Yttria partially-stabilized Zirconia (3YZ) ceramic ink that produces parts with both nano and microporosity and is compatible with two AM techniques: DIW and projection microstereolithography (PμSL). The 3YZ nano-porous ceramic printed parts had engineered macro cavities measuring several millimeters in length, wall thicknesses ranging from 200 to 540 μm, and…

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NIF Target Chamber

This invention concerns a new type of optic: a transient gas or plasma volume grating produced indirectly by small secondary lasers or directly by nonlinear processes using the primary beams themselves. When used in conjunction with advantageously placed shielding it offers a means of protecting the final optical components of a high-repetition-rate IFE facility. These transmission optics are…

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optical element

This invention utilizes transmission gratings to combine lasers of the same wavelength into a single collinear output. The transmission grating can be an all-bulk structure fabricated in fused silica, silicon, diamond, silicon nitride, etc. The transmission grating can also have dielectric coatings to increase diffraction efficiency and optical bandwidth. This invention makes possible…

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Radio Frequency Photonics Optimizes Signal Processing

LLNL researchers in the NIF Directorate DoD Technologies RF Photonics Group explored phase modulation solutions to this signal processing challenge. Optical frequency combs offer phase noise characteristics that are orders of magnitude lower than available from commercial microwave references. The Photonics Group researchers recognized that by converting the intensity information into phase,…

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Microcapsules offer high surface area and a superior delivery system.

This invention describes a multiple nozzle microfluidic unit that allows simultaneous generation streams of multiple layered coaxial liquid jets. Liquids are pumped into the device at a combined flow rate from 100 mL/hr to 10 L/hr. Droplets are created with diameters in the range of 1 µm to 5 mm and can be created with 1-2 shell layers encapsulating fluid. Droplets created from the system can…

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Plasma wind
CRETIN is a 1D, 2D, and 3D non-local thermodynamic equilibrium (NLTE) atomic kinetics/radiation transport code which follows the time evolution of atomic populations and photon distributions as radiation interacts with a plasma consisting of an arbitrary mix of elements. It can provide detailed spectra for comparing with experimental diagnostics.
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creation of ultra-high energy density matter by an intense laser pulse
Livermore Lab researchers have developed two new methods for improving the efficiency of laser drilling. The first method is based on multi-pulse laser technology. Two synchronized free-running laser pulses from a tandem-head Nd:YAG laser and a gated CW laser are capable of drilling through 1/8-in-thick stainless-steel targets at a standoff distance of 1 m without gas-assist. The combination of a…
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grating_optic2

Livermore Lab's SBC grating optics benefit from the combination of the following key technologies:

  • LLNL proprietary optical coating designs utilizing >100 thin film layers – enables ultra-low-loss, ppm transmission levels through the coating, high diffraction efficiency, and large bandwidth.
  • LLNL proprietary dispersive surface relief structure…
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bacteria-based_synthetic_u_detection_pathway

Using native bacterial regulatory systems, LLNL researchers have developed whole-cell biosensors that can be used in aqueous samples for sensitive and selective in situ detection of the uranyl oxycation (UO22+), the most toxic and stable form of U in oxygenated environments. Specifically, two functionally independent, native U-responsive regulatory systems, UzcRS and UrpRS, were integrated…

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monolithic_telescope

Monolithic Telescopes are a novel implementation of a solid catadioptric design form, instantiated in a monolithic block of fused silica.

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geothermal steam exhaust

LLNL has a patented process to produce colloidal silica directly from geothermal fluids. Livermore’s process uses membranes to produce a mono-dispense slurry of colloidal silica particles for which there are several applications. LLNL has demonstrated that colloidal silica solutions that result from extraction of silica from geothermal fluids undergo a transition to a solid gel over a range of…

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Optics

The LLNL method for optimizing as built optical designs uses insights from perturbed optical system theory and reformulates perturbation of optical performance in terms of double Zernikes, which can be calculated analytically rather than by tracing thousands of rays. A new theory of compensation is enabled by the use of double Zernikes which allows the performance degradation of a perturbed…

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gradient_composition_glass

LLNL researchers have developed a custom resin formulation which uses a dispersing solvent and only a multifunctional monomer as the binding agent. The dispersing solvent system typically used has multiple components meant to achieve excellent dispersal of silica in order to create a flowable resin (rather than a paste). The dispersing agent has low vapor pressure, which allows the 3D printed…

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3D printed electrodes

Nanomaterials that are emerging out of cutting edge nanotechnology research are a key component for an energy revolution. Carbon-based nanomaterials are ushering in the "new carbon age" with carbon nanotubes, nanoporous carbons, and graphene nanosheets that will prove necessary to provide sustainable energy applications that lessen our dependence on fossil fuels.

Carbon aerogels (CAs)…

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 San Joaquin River headwaters

LLNL has developed a noble gas mass spectrometry facility that houses a state-of-the-art water-gas separation manifold and mass spectrometry system designed specifically for high throughput of groundwater samples. The fully automated, computer-controlled manifold system allows analysis of the full suite of noble gases (3He/4He, He, Ne, Ar, Kr, and Xe concentrations), along with low level…

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fte_cd
LLNL has developed an innovative technology known as flow-through electrode capacitive desalination (FTE-CD) that promises to unlock an almost inexhaustible water source for U.S. and global population markets. FTE-CDI represents a robust and low-maintenance path for efficiently and cost-effectively producing clean drinking water from seawater and brackish water.
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Space-based Telescopes for Actionable Refinement of Ephemeris (STARE)

LLNL is developing the Space-based Telescopes for Actionable Refinement of Ephemeris (STARE). STARE is a constellation of low cost nano-satellites (less than 5Kg) in low-earth orbit dedicated to the observation of space debris in conjunction with a ground-based infrastructure for maintenance, coordination and data processing. Each nano-satellite in the constellation is capable of recording an…

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 laser-Compton test station

The selected industrial partner and LLNL will enter into a Cooperative Research and Development Agreement (CRADA) to develop the next generation of laser technologies for MEGa-ray systems and to create a next generation of MEGa-ray sources that could be marketed to both the industrial and academic communities.

The MEGa-ray system developed will be based on LLNL's proprietary, multi-…

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ceramic_filter

A ceramic HEPA filter designed to meet commercial and DOE requirements, as well as to minimize upgrade installation logistics for use in existing facilities. Current key performance requirements are described in DOE Standard 3020. The ceramic filter is designed to be nonflammable, corrosion resistant, and compatible with high temperatures and moisture. The ceramic filter will significantly…

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nuclear reactor

The new LLNL technique works by transiently removing and trapping concrete or rock surface material, so that contaminants are confined in a manner that is easy to isolate and remove. Our studies suggest that 10 m2 of surface could be processed per hour. The technique easily scales to more surface/hr.

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Hand polishing optics

LLNL's Slurry Stabilization Method provides a chemical means of stabilizing a polishing compound in suspension at working concentrations without reducing the rate of material removal. The treated product remains stable for many months in storage.

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Transformer

An invention at LLNL uses a mixture of solid and liquid dielectric media. This combination has properties that are an improvement over either separately. The solid phase, in the form of small pellets, inhibits fluid motion, which reduces leakage currents, while the liquid phase (dielectric oil) provides self-repair capabilities. Also, since the media is removable, the high voltage equipment…