This LLNL invention is capable of generating, on-the-fly, tunable magnetic field strengths with voxel-by-voxel alignment. The approach is to use a custom designed Halbach array consisting of permanent magnets or electromagnets to provide a uniform magnetic field in any direction. This Halbach array will then be coupled with a stereolithography (SLA) printer so that locally aligned…
Keywords
- Additive Manufacturing (51)
- 3D Printing (7)
- Substrate Engraved Meta-Surface (SEMS) (7)
- Compact Space Telescopes (5)
- Diode Lasers (4)
- Laser Materials Processing (4)
- Precision Optical Finishing (4)
- Optical Damage Mitigation (3)
- RF Photonics (3)
- Synthesis and Processing (3)
- Additively Manufactured (AM) Optics (2)
- Fiber Lasers (2)
- Manufacturing Automation (2)
- Manufacturing Improvements (2)
- Microfabrication (2)
- Ultrashort Pulse Lasers (2)
- Volumetric Additive Manufacturing (2)
- Inertial Confinement Fusion (ICF) (1)
- Manufacturing Simulation (1)
- Precision Engineering (1)
Technology Portfolios

LLNL researchers have developed additive manufactured fuel targets for IFE. They have been successful in using TPL to fabricate low density (down to 60 mg/cm3) and low atomic number (CHO) polymeric foams for potential targets, and some have been tested at the OMEGA Laser Facility. With TPL, LLNL researchers have also been able to fabricate a full fuel capsule with diameter of ~ 5mm or…

The approach is to use appropriately doped semi-insulating gallium nitride to provide a high damage tolerant photoconductor with high responsivity to various pump wavelength light. Mn, C, or Fe are used as dopants to provide a source of electrons or holes that can be excited. This is combined with the use of dichroic antireflection coating at the GaN/polyimide/liquid crystal…

LLNL researchers have developed a silicone based conductive, elastomeric 3D DIW printed structure with a lower wt.% conductive, composite filler to allow for the creation of 3D printed lattice structures with tunable conductivity. The conductivity of the printed structure can be varied using composition of the starting DIW ink formulation as well as the 3D printed spacing and…

This LLNL invention allows for the fabrication of complex waveplate features and topologies from fused silica, a highly desirable and durable waveplate material. It also is a unique technique for density multiplication and high-fidelity bidirectional deposition, which can create optical components that are generally for entirely new classes of optical materials.
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This LLNL invention is comprised of (1) a volumetric subtractive manufacturing system which can tomographically manufacture 3D structures with negative features (materials in negative space is degraded with light exposure), and (2) a hybrid volumetric additive/subtractive manufacturing system in which a gelled/solid structure is printed by resin material polymerization using one light, and…

This invention focuses on the design of a fully interchangeable hub-droplet device apparatus for multiple droplet generation in parallel. The novel central hub combined with interchangeable chip configuration allows the use of different planar droplet generation devices that can be replaced and exchanged as needed. By separating the central housing hub which distributes incoming liquids into…

LLNL researchers have developed a parallelized TPP system that combines metalens array and spatial light modulator (SLM) to manipulate the directed laser light, which enables high-volume fabrication of nano-architected structures at wafer-scale. Instead of using a single microscope objective, LLNL’s approach uses an array of metalens that the laser passes through with each metalens being…

The approach is to use quantitative phase imaging (QPI) using a common-path phase-shifting interferometry technique. A sequence of four phase shifts with an increment of π/2 between unscattered reference beam and scattered sample beam are imparted by a spatial light modulator. A quantitative phase image is retrieved from four raw intensity images. QPI is a highly sensitive…

This LLNL invention proposes a new microstructured large mode area fiber design that enhances the confinement of the core mode while strongly suppressing thermal or scattering mediated dynamic couplings with higher order modes thought to be responsible for generating undesirable Transverse Mode Instabilities. The design accomplishes higher order mode suppression and core mode confinement by…

LLNL researchers developed a novel strategy that involves material transformations such as oxidation, nitridation, or carbonization. In one embodiment, copper is heated under ambient conditions resulting in its surface being oxidized and turned into copper oxide, where a new material (e.g., copper oxide) is developed via transformation (e.g., oxidation) without additional addition deposition…

LLNL researchers have developed a piezo-driven jetting powder AM method that provides better control of the packing of printed powder. Powder is fed via a stainless-steel hopper to a nozzle; at the narrowest necking point the powder jams, and flow ceases. A vibrating piezoelectric element (with through-thickness vibration mode) is driven by a 150V AC signal to disturb the jammed powder,…

LLNL researchers have developed a method which utilizes functional alcohols to depolymerize polyurethane crosslinked networks. The functional alcohols show 5X increase in the depolymerization efficiency compared with current state of art (e.g. methanol, ethylene glycol). The crosslinked polyurethane networks completely depolymerized into a liquid oligomer within 48 hours at ambient…

LLNL researchers have developed a novel photocurable silicone useful for producing three-dimensional objects via additive manufacturing. The resin formulations consist of a mult-component siloxane polymers with different functionalities, a platinum catalyst, a photoinitiator, and other organic peroxides. The LLNL invention involves controlling the spatial and temporal aspects of the…

Nozzle design and manufacturing greatly affects the performance of LMJ printers. This LLNL invention describes a novel multi-part nozzle design that improves their performance.
The approach that LLNL researchers developed involve:

LLNL researchers have created a suitably compliant adhesive that is based on a thiol monomer mixed with an epoxy monomer in the presence of metal oxide nanoparticles. When cured into films or pucks, the adhesives are optically transparent with a RI up to ~1.68 at 532 nm with varying shore A hardness in the range of 50 to 98. The adhesive can potentially be mixed and potted between Ti:…

LLNL researchers have continued to develop their pioneering DIW 3D-printed glass optics technology that allows for the 3D printing of single- and multi-material optical glass compositions in complex shapes. This LLNL invention further proposes incorporating dopants (including, but not limited to TiO2 and Pd) into slurries and inks for 3D printing of glass components that can then be directly…

LLNL researchers developed an approach that uses a Z-pinch magnetohydrodynamic (“ZMHD”) pulse as the pressure pulse to emit the liquid metal droplets. ZMHD produces a large current pulse to traverse a column of conducting liquid metal. This pulse induces a magnetic field through Ampere’s law, and that field then interacts with the current pulse via the Lorentz force to generate a…

This LLNL invention concerns a method for patterning the index of refraction by fabricating a spatially invariant metasurface, and then apply spatially varied mechanical loading to compress the metasurface features vertically and spread them radially. In doing so, the index of refraction can be re-written on the metasurface, thus enabling index patterning. This process allows rapid 'rewriting…

This invention, hereby called liquid metal binder jetting (LMBJ), uses a molten metal as the “binder” that is deposited on ceramic powder, resulting in a multi-material fabrication process that includes both the ceramic and metallic phase in the same process. The simple process involves four steps:

This invention proposes achieving the same effect of a single, high intensity pulse through the use of a closely spaced burst of short duration pulses. By keeping the intensity of the individual pulses below the damage threshold the risk of catastrophic damage is greatly mitigated. Additionally, the pulses are directed to strike the target at locations temporally and spatially sufficiently…

Holography fully encodes a 3D light field by imprinting its interference pattern with a reference laser beam in a nonlinear medium. By crossing two pump laser pulses in a gas jet, a hologram can be recorded as a distribution of plasma, allowing manipulation of a subsequent high-intensity probe beam. The interference between two collinear beams with distinct foci produces a plasma zone plate, a…

This invention proposes the use of a nonlinear spectral broadening subsystem as a post-CPA pulse compression add-on for high energy laser systems. The proposed solution utilizes the beam profile of a high peak power laser as a reference to shape a highly transmissive nonlinear plastic (e.g., CR39) itself to ensure a spatially homogeneous nonlinear spectral broadening.

Powder atomic layer deposition process is used to coat nanopowders of host materials (e.g. yttrium aluminum garnet) with optically active neodymium organometal precursor followed by O2/O3 RF plasma to convert to a single layer of Nd2O3. The process can be repeated to build arbitrarily thick layers with custom doping profiles and followed by post-…

This novel invention specifically enables the fabrication of arbitrarily tailored birefringence characteristics in nano-structured meta-surfaces on non-birefringent substrates (e.g. fused silica). The birefringent nano-structured meta-surface is produced by angled directional reactive ion beam etching through a nano-particle mask. This method enables the simultaneous tailoring of refractive…

This invention (US Patent No. 11,294,103) is an extension of another LLNL invention, US Patent No. 10,612,145, which utilizes a thin sacrificial metal mask layer deposited on a dielectric substrate (e.g. fused silica) and subsequently nanostructured through a laser generated selective thermal de-wetting process.

This invention proposes fabrication of a sandwich of two or more (typically 3) magneto-rheologically finished (MRF’d) birefringent plates with purpose designed arbitrary surface contour profiles and eigen-axis orientation. The tailored surface contour profiles are designed to compensate for the observed de-polarization characteristics of a particular solid-state laser operating in a particular…

LLNL researchers have designed and produced, both conductive and non-conductive porous electrode components manufactured for improved metal deposition, discharging, and fluid dynamics in hybrid flow batteries. This is achieved through Direct Ink Writing (DIW) additive manufacturing. The engineered 3D electrodes enable uniform current distribution and even metal deposition during…

LLNL researchers have enhanced and expanded the IDEA technology, which fabricates micron-scale droplets that are then crosslinked in-air (within milliseconds) using a UV light source before collection. An aerodynamically shearing air jet or acoustic vibration force causes rapid droplet formation.

This LLNL invention is an optical amplifier, wherein the gain element is in the form of a frustum and a spherically diverging laser beam is introduced into the gain medium via the small face of the frustum. In one embodiment, the pump beam is generated by one or more chromium-lasers that are counter-propagating, having been introduced through the large face of the frustum. The gain medium may…

LLNL’s invention is a photopolymerizable polymer resin that consists of one or more nitrile-functional based polymers. The resin is formulated for SLA based 3D printing allowing for the production of nitrile-containing polymer components that can then be thermally processed into a conductive, highly graphitic materials. The novelty of the invention lies in (1) the photo-curable nitrile-…

This invention circumvents the GMAPD deadtime limitation by using an array of GMAPDs in a non-imaging configuration instead of a single element. By using an array, with sufficient number of elements, guarantees there is always at least one element available to detect an incoming photon even if others are in the deadtime zone.

This invention works by imaging an ultrafast pulse diffracted from a large grating onto a spatial light modulator (SLM) thereby directly transcribing an arbitrary record on a pulse front tilted (PFT) ultrafast pulse. The grating generates PFT of the input pulse, and the SLM provides temporal control of the pulse through the space-to-time mapping of the tilted pulse. Coupling this patterned…

LLNL researchers refined custom mixing techniques and formulations in order to avoid clumping and fiber agglomerations for a flowable tailored feedstock that produces a homogeneous, survivable thermal barrier coating. Formulation improvements coupled with unexpected nozzle coupling from Buchi spray dry components leads to the production of fiber containing spray dried feedstock that can…

LLNL researchers have developed a fabrication process for creating 3D random interdigitated architectures of anodes and cathodes, eliminating the need for a membrane to separate them. This approach is similar to the repeating interdigitated multi-electrode architectures that also were developed at LLNL.

This invention exploits the non-linearities of optical Mach-Zehnder (MZ) electrooptic modulators to enhance small signal dynamic range at higher bandwidths. A linear photodiode (PD) converts the amplified optical signal output from the MZ back to an electrical signal completing an Electrical-Optical-Electrical (EOE) conversion cycle. The dynamic range can be further enhanced by daisy chaining…

This invention draws on the higher damage tolerance of plasma to manipulate high-intensity light. Plasma is a difficult medium to control and sets stringent limits on optical performance. A compact high-power laser system can be realized using plasma transmission gratings for chirped pulse compression based on currently achievable plasma properties and minimal plasma volume. A double…

This invention proposes a volumetric transmission grating based on ionization created in a neutral gas by crossing and interfering two short-pulse pump lasers so that their intensity maxima rise above the medium’s ionization threshold. This will create a modulated index of refraction that can diffract a subsequent probe beam like a transmission grating. Crucially for the application of…

LLNL’s invention combines four approaches to enable on-the-fly multi-resolution metal droplet printing: (1) a nozzle with two or more orifices of varying diameter and length, (2) a set of corresponding pressure pulses that can eject droplets out of some, but not all, orifices in either magnetohydrodynamic (MHD-LMJ) or Pneumatic-LMJ, (3) the ability to change the pressure pulse on demand…

This invention proposes using a pulse laser configured to generate laser pulses and a controller for controlling operation of the pulse laser. The controller is further configured to control the pulse laser to cause the pulse laser to generate at least one of the laser pulses with a spatiotemporally varying laser fluence over a duration of at least one of the laser pulses. The spatiotemporally…

Rapid monolith development at scale is achieved through use of a functionally equivalent optic simulant made from a low-cost material to substitute the functional optic. Monolith optical performance is affected not only by thermal expansion but also by temperature inhomogeneity due to the temperature dependence of refractive index.

Aeroptics are a proposed new class of monolithic optical system in aerogel fabricated by molding around a master mandrel. This approach combines the intrinsic stability of proven monolithic telescopes, with the ultralow density of silica aerogels. In Aeroptics, the monolith is hollow with an aerogel substrate providing a supporting structure. Theoretically, Aeroptics could enable 1-m aperture…

This invention proposes to engineer the current density along the length of a laser diode to overcome the penalty associated with non-uniformity resulting from asymmetry in the gain, photon or carrier density despite having uniform contact. Optimizing the current density profile enables diode lasers to operate with greater power conversion efficiency or operate with equivalent power conversion…

This invention proposes to engineer the temperature dependence of the emission wavelength of LEDs and laser diodes. The approach is to use a strain-inducing coating to counteract the intrinsic temperature coefficient of the emission wavelength of the LED or laser diode device thereby rendering it athermal. This invention avoids additional complexity, size, weight and power dissipation of…

This invention proposes a method to overcome the key limitation of electrically pumped lasers based on AlN, AlGaN, or AlInGaN, namely the lack of suitable shallow donor and acceptor dopants. As the band gap of these materials increases (and the emission wavelength decreases), both electrons and holes require greater thermal energies in order to ionize.

Laser diode lensing effect can be substantially reduced by creating a pattern interface such that the substrate is only attached at the diode mesa. This is achieved by either creating a pattern solder joint and/or pattern substrate.

LLNL researchers’ approach to this challenge is to design a modular valve subsystem that redirects the flow away from the main nozzle to an “exhaust”. By re-routing the flow to a different exit port, steady state flow can be better maintained. The re-routing requires actuators that work in tandem; open and close of the nozzle and exhaust valves have to be executed simultaneously. …

LLNL researchers developed novel workflows where material is first cast into the LCE molds at room temperature. Upon curing, the mold is induced to expand or contract (change shape) by external stimuli (light, heat, solvent) to self-release. A reduction to practice example used silica-loaded silicone ink casted into a LCE cylinder mold. It was cured at 100°C, and self-…

LLNL researchers have developed an innovative and uniform single-pot polymer multi-material system, based on a combination of 3 different reactive chemistries. By combining the three different constituent monomers, fine control of mechanical attributes, such as elastic modulus, can be achieved by adjusting the dosage of UV light throughout the additive manufacturing process. This…

Three important aspects of this invention are: (1) the formulation of a photocurable resin containing a fluorophore that exhibits AIE behavior; (2) the method of in-situ and real-time characterization for monitoring the reaction kinetics during the photopolymerization and UV-curing process; and (3) the application of a new 3D steganographic ink for 3D encrypted structure.
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This invention takes advantage of the high water-solubility of key NIF KDP crystal optics and uses water as an etchant to remove surface defects and improve the laser induced damage threshold. Since pure water etches KDP too fast, this invention is to disperse water as nanosized droplets in a water-in-oil micro-emulsion. While in a stable micro-emulsion form, the surfactant additives prevent…
This invention proposes to use laser induced melting/softening to locally reshape the form of a glass optic. The local glass densification that results induces predictable stresses that through plate deformation mechanics yield a deterministic methodology for arbitrarily reshaping an optic surface figure and wavefront without the need to remove material.

This invention achieves both a wider field of view and faster f-number within a monolithic substrate by incorporating an aspheric convex refractive first surface and a planar aspheric field corrector surface on the final refractive surface. These two refractive surfaces work in conjunction with a concave aspheric primary and convex aspheric secondary mirror (e.g. Cassegrain type) to improve…

This invention is about a Material Jetting technique used to form a ceramic green body that is subsequently processed into a transparent ceramic optic with unique tunable spatial control of the composition as a function of position only achievable via additive manufacturing methods. This method uses ceramic particles loaded into a liquid slurry with required viscosity and surface tension to be…

This invention consists of a method of forming nanoscale metal lines to produce a grating-like mask with wide area coverage over the surface of a durable optical material such as fused silica. Subsequent etching processes transfer the metal mask to the underlying substrate forming a birefringent metasurface. This method enables the production of ultrathin waveplates for high power laser…

This LLNL invention proposes a novel approach to spectral interferometry, the preferred technique for characterizing nanosecond long records of laser pulse shapes with femtosecond resolution. Linear techniques are much more sensitive than the many nonlinear techniques of the prior art and can be used for very weak pulses. However, they depend on being able to interfere the signal with a well…

LLNL has designed and demonstrated a novel transmission Spectral Beam Combining grating optic assembly with megawatt power handling capabilities. The design consists of a monolithic structure with an input transform optic and an output transmission grating. The design features LLNL’s proven compact, lightweight Spectral Channels Splicer architecture to combine adjacent spectral channels of…

The approach involves 3D printing hinges made of Pre-Stressed Polymers (“PSP”) onto polyimide (“PI”) substrates. These hinges are then able to fold in response to externally applied stimuli, such as light. First, 2D PI devices will be microfabricated. Then, PSP infused with colored inks will be printed using Direct Ink Write (“DIW”) on the hinges of the PI devices. When…
Heat sensitive materials such as piezoelectric and MEMS devices and assemblies, magnetic sensors, nonlinear optical crystals, laser glass or solid-state laser materials, etc. cannot be exposed to excess temperatures which in the context of this invention, means materials that cannot be exposed to temperatures greater than 50°C (122°F). LLNL’s invention describes a low-temperature method of…

LLNL’s approach to meet this challenge is to use a pneumatic DOD-LMJ method wherein the nozzle is filled with a molten pure metal or metal alloy. There are two reservoirs in LLNL’s invention that are in direct contact with each other: the liquid metal reservoir that is constantly heated so the metal remains molten and an inert gas reservoir, which is connected to an inert gas pressure…

LLNL researchers have developed novel advanced manufactured biomimetic 3D-TPMS (triply periodic minimal surface) membrane architectures such as a 3D gyroid membrane. The membrane is printed using LLNL's nano-porous photoresist technology. LLNL’s 3D-TPMS membranes consist of two independent but interpenetrating macropore flow channel systems that are separated by a thin nano-porous wall…

Electrodes that measure current and voltage are connected to the LPBF build plate by magnetic metal arms. These arms are placed on a steel weighted base that provides a high degree of mechanical flexibility to conform to small geometries and can be easily incorporated into a complex manufacturing system. Furthermore, the electrodes are connected to tapered copper tips that can…

LLNL has co-developed a number of technologies thatuse cold spray deposition that enable new designs for functional materials with low waste.

The novel approach is to make Ultem® into an ink for DIW or droplet printing by dissolving Ultem® in solvents, such as tetrahydrofuran. This produces a viscous solvent-melt that is loaded into an ambient temperature extrusion system and deposited into a defined structure by the 3D printer. Solvent mobility is limited by the polymer structure, and further solvent removal allows…

LLNL’s novel approach is to use Direct Ink Write (DIW) with a co-extrusion nozzle to enable the extrusion of multiple materials as one coil. With this method, LLNL researchers were able to produce an insulating wire that is composed of three different materials, axial conducting and insulating from its inner core to its outer sheath. After heat treatment, the printed wireI was then…

Beam Element-based Topology Optimization (“BETO”) is one of the conventional ways to design microstructures. It starts with an initial design that is composed of many beam elements. LLNL’s invention uses accurate Component-wise Reduced Order Models (“CWROM”) rather than the inaccurate beam elements. In doing so, the process becomes computationally efficient and fast, as each…

LLNL’s novel approach is to use waveguide-based devices and microwave energy to perform characterization of the projectile or droplet. Various embodiments of droplet devices can determine the size, motion (position, velocity, and acceleration), rate, and material elements of a moving element. This invention uses a tubular housing having a first end (input port) and a second end (…

LLNL’s approach to designing logic gates uses heuristic as well as with the Freedom and Constraint Topologies (FACT) methods; these gates are then produced using existing additive manufacturing processes. The 10,122,365 and 10,678,293 patents describe how to fabricate the gates; the

LLNL’s approach is to design and fabricate a massively-parallel microanode printhead using a custom complementary metal-oxide semiconductor integrated circuit (CMOS IC) chip with independent electronics for each pixel. This microanode in close proximity to the cathode surface will electroplate dissolved ions into a small voxel. The probe then moves and continues to deposit material…

LLNL researchers have developed an approach is to use pneumatic droplet ejection devices to rapidly 3D print solid metal parts that also have a smoother surface finish than conventional liquid metal printing. Pneumatic droplet ejection printers can be used in two different modes: “droplet mode” uses pulsed gas pressure to create individual droplets of liquid metal that are collected to…

LLNL researchers have developed a high average power Faraday rotator that is gas-cooled and uniquely designed to dissipate heat uniformly so that it does not build up in the optical component and affect its performance. The Faraday rotator material is sliced into smaller disks like a loaf of bread so that high speed helium gas can flow between the slices. With this highly efficient…

LLNL has developed a process to partially sinter starting material composed of smaller-sized powder particles to obtain a loose powder product that have larger-sized particles. To avoid the undesired formation of a single fully-sintered piece, the starting powder material is heated for a relatively shorter time. The time and temperature required for partial sintering is…

Improving the active material of the Zn anode is critical to improving the practicality of Zn-MnO2 battery technology. LLNL researchers have developed a new category of 3D structured Zn anode using a direct-ink writing (DIW) printing process to create innovative hierarchical architectures. The DIW ink, which is a gel-based mixture composed of zinc metal powder and organic binders, is…

This novel detector for characterizing IFE implosions is an alternative to the current RTNADs to measure neutron fluxes > 3x1011 neutrons/cm2 at high shot rates. The detector consists of a stack of small square metal wafers separated by thin insulating spacers. Every other wafer is held at high voltage while the remaining wafers are grounded. The stack acts as an…

To overcome challenges that existing techniques for creating 3DGs face, LLNL researchers have developed a method that uses a light-based 3D printing process to rapidly create 3DG lattices of essentially any desired structure with graphene strut microstructure having pore sizes on the order of 10 nm. This flexible technique enables printing 3D micro-architected graphene objects with complex,…

The novel approach developed by LLNL researchers is to use an electric field as the non-contact-based powder remover. The main components of the remover are an electrode and a dielectric layer. As the remover moves across the stage, a high voltage is applied to the electrode that forms an electric field between the electrode and the powder bed. Under the influence of the…

LLNL’s novel approach utilizes a number of techniques to improve reconstruction accuracy:
- Better coding scheme-based techniques
- Hardware-assisted techniques
- Adaptive fringe projection techniques
- Multi-exposure based techniques
The method requires specific calibration procedures and control of the hardware, which is achieved through a digital twin…

This novel AM approach utilizes cavitation bubbles generated within liquid resin by ultrasonic energy that trigger, induce, or catalyze a polymerization process (3D Ultrasound Polymerization). Ultrasound may be generated by piezoelectric transducers or high-power lasers and by modulating the ultrasound wave (frequency and amplitude), the cavitation site could be directed.

LLNL’s MVAM method comprises of a microwave applicator array coupled to a time-reversal beam steering algorithm to focus and deposit microwave energy in the feedstock material. The selective focusing of high-power microwave fields results in delivery of localized energy to arbitrary regions in a 3D volume. The localized area in the 3D volume heats up, allowing for the curing,…

The approach is to combine the techniques of 3D printing aligned carbon fiber composites and melt-3D printing of glasses in a non-obvious manner to allow 3D printing (with controlled microstructure, fiber alignment, complex geometries, and advanced second order composite properties) of a new class of additively manufactured fiber-glass composites. It involves four major elements: …

LLNL’s approach to producing refractive index matching (RIM) resin is to use a commercially available material known as polyhedral oligomeric silsesquioxane (POSS) precursors. To tune the refractive index, POSS can be functionalized with additives such as phenylthiol, until the refracted index match is achieved. For example, for a 1.4 NA oil objective lens, a RIM resin with a…

To get the best of both worlds – the sensitivity of LC-MS with the speed of PS-MS – and a functional substrate that can maintain sample integrity, LLNL researchers looked to 3D printing. They have patented a novel approach to create lattice spray substrates for direct ionization mass spectroscopy using 3D-printing processes.

LLNL researchers, through careful control over the chemistry, network formation, and crosslink density of the ink formulations as well as introduction of selected additives, have been successful in preparing 3D printable silicone inks with tunable material properties. For DIW (direct in writing) applications, LLNL has a growing IP portfolio around 3D printable silicone feedstocks for…

This invention discloses a method to minimize transient variations in the wavelength- and/or pointing-behavior of an optic, without requiring a reduction in its thermal resistance, optical absorption, or operating irradiance. The invention employs a combination of a time-varying heat source and time-varying thermal resistance and/or heat sink temperature to achieve temperature stability of the…

This novel method of producing waveplates from isotropic optical materials (e.g. fused silica) consists of forming a void-dash metasurface using the following process steps:

This invention concerns a new type of optic: a transient gas or plasma volume grating produced indirectly by small secondary lasers or directly by nonlinear processes using the primary beams themselves. When used in conjunction with advantageously placed shielding it offers a means of protecting the final optical components of a high-repetition-rate IFE facility. These transmission optics are…

This invention utilizes transmission gratings to combine lasers of the same wavelength into a single collinear output. The transmission grating can be an all-bulk structure fabricated in fused silica, silicon, diamond, silicon nitride, etc. The transmission grating can also have dielectric coatings to increase diffraction efficiency and optical bandwidth. This invention makes possible…

LLNL researchers in the NIF Directorate DoD Technologies RF Photonics Group explored phase modulation solutions to this signal processing challenge. Optical frequency combs offer phase noise characteristics that are orders of magnitude lower than available from commercial microwave references. The Photonics Group researchers recognized that by converting the intensity information into phase,…

LLNL’s method of 3D printing fiber-reinforced composites has two enabling features:

MBD captures the complete specification of a part in digital form and leverages (at least) the universal STEP file format. MBD has revolutionized manufacturing due to time and cost savings associated with containing all engineering data within a single digital source. LLNL researchers have been able to develop a novel encoding method to transform digital definitions in any given STEP file into…




Livermore Lab's SBC grating optics benefit from the combination of the following key technologies:
- LLNL proprietary optical coating designs utilizing >100 thin film layers – enables ultra-low-loss, ppm transmission levels through the coating, high diffraction efficiency, and large bandwidth.
- LLNL proprietary dispersive surface relief structure…

LLNL researchers have designed and tested performance characteristics for a multichannel pyrometer that works in the NIR from 1200 to 2000 nm. A single datapoint without averaging can be acquired in 14 microseconds (sampling rate of 70,000/s). In conjunction with a diamond anvil cell, the system still works down to about 830K.

LLNL has developed a system and method that accomplishes volumetric fabrication by applying computed tomography (CT) techniques in reverse, fabricating structures by exposing a photopolymer resin volume from multiple angles, updating the light field at each angle. The necessary light fields are spatially and/or temporally multiplexed, such that their summed energy dose in a target resin volume…


Monolithic Telescopes are a novel implementation of a solid catadioptric design form, instantiated in a monolithic block of fused silica.

LLNL has developed an optically clear iodine-doped resist that increases the mean atomic number of the part. AM parts fabricated with this resist appear radio-opaque due to an increase in the X-ray attenuation by a factor of 10 to 20 times. Optical clarity is required so that the photons can penetrate the liquid to initiate polymerization and radio opacity is required to enable 3D computed…

LLNL has solved the challenges of depth-resolved parallel TPL by using a temporal focusing technique in addition to the spatial focusing technique used in serial writing systems. We temporally focus the beam (through optical set-up design) so that a sharp Z-plane can be resolved while projecting 2D “light sheets” that cause localized photo-polymerization. This enables printing of complex 3D…

The LLNL method for optimizing as built optical designs uses insights from perturbed optical system theory and reformulates perturbation of optical performance in terms of double Zernikes, which can be calculated analytically rather than by tracing thousands of rays. A new theory of compensation is enabled by the use of double Zernikes which allows the performance degradation of a perturbed…

By combining 3D printing and dealloying., researchers at LLNL have developed a method for fabricating metal foams with engineered hierarchical architectures consisting of pores at least 3 distinct length scales. LLNL’s method uses direct ink writing (DIW), a 3D printing technique for additive manufacturing to fabricate hierarchical nanoporous metal foams with deterministically controlled 3D…

LLNL researchers have developed a custom resin formulation which uses a dispersing solvent and only a multifunctional monomer as the binding agent. The dispersing solvent system typically used has multiple components meant to achieve excellent dispersal of silica in order to create a flowable resin (rather than a paste). The dispersing agent has low vapor pressure, which allows the 3D printed…


LLNL scientists have developed a new metal additive manufacturing technique that uses diode lasers in conjunction with a programmable mask to generate 2D patterns of energy at the powder surface. The method can produce entire layers in a single laser shot, rather than producing layers spot by spot as is currently done in powder bed fusion methods.

The new LLNL technique works by transiently removing and trapping concrete or rock surface material, so that contaminants are confined in a manner that is easy to isolate and remove. Our studies suggest that 10 m2 of surface could be processed per hour. The technique easily scales to more surface/hr.

LLNL's Slurry Stabilization Method provides a chemical means of stabilizing a polishing compound in suspension at working concentrations without reducing the rate of material removal. The treated product remains stable for many months in storage.


The selected industrial partner and LLNL will enter into a Cooperative Research and Development Agreement (CRADA) to develop the next generation of laser technologies for MEGa-ray systems and to create a next generation of MEGa-ray sources that could be marketed to both the industrial and academic communities.
The MEGa-ray system developed will be based on LLNL's proprietary, multi-…

LLNL is developing the Space-based Telescopes for Actionable Refinement of Ephemeris (STARE). STARE is a constellation of low cost nano-satellites (less than 5Kg) in low-earth orbit dedicated to the observation of space debris in conjunction with a ground-based infrastructure for maintenance, coordination and data processing. Each nano-satellite in the constellation is capable of recording an…